{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:53Z","timestamp":1736831573784,"version":"3.33.0"},"reference-count":7,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,23]],"date-time":"2014-07-23T00:00:00Z","timestamp":1406073600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,23]],"date-time":"2014-07-23T00:00:00Z","timestamp":1406073600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>The asymmetric unit of the title compound, C<jats:sub>49<\/jats:sub>H<jats:sub>36<\/jats:sub>O<jats:sub>6<\/jats:sub>\u00b7CHCl<jats:sub>3<\/jats:sub>, contains half an organic molecule, the complete molecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloroform molecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in<jats:italic>PLATON<\/jats:italic>[Spek (2009).<jats:italic>Acta Cryst<\/jats:italic>. D<jats:bold>65<\/jats:bold>, 148\u2013155]; the unit-cell characteristics take into account the presence of CHCl<jats:sub>3<\/jats:sub>. The dihedral angles between the planes of the naphthalene ring system and the methoxybenzene rings are 71.05\u2005(7) (<jats:italic>syn<\/jats:italic>to the central C=O group) and 57.27\u2005(6)\u00b0 (<jats:italic>anti<\/jats:italic>to the central C=O group). In the crystal, molecules are linked by C\u2014H...O interactions, generating<jats:italic>C<\/jats:italic>(12) chains running parallel to the<jats:italic>b<\/jats:italic>axis.<\/jats:p>","DOI":"10.1107\/s1600536814016389","type":"journal-article","created":{"date-parts":[[2014,7,22]],"date-time":"2014-07-22T08:07:33Z","timestamp":1406016453000},"page":"o873-o874","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0<sup>2,11<\/sup>.0<sup>4,9<\/sup>.0<sup>15,20<\/sup>]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"S.","family":"Gopinath","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"P.","family":"Narayanan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K.","family":"Sethusankar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Meganathan","family":"Nandakumar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arasambattu K.","family":"Mohanakrishnan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,7,23]]},"reference":[{"key":"tk5322_bb1","unstructured":"Bruker (2008). 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