{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T09:13:40Z","timestamp":1759742020706,"version":"3.33.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2014,10,4]],"date-time":"2014-10-04T00:00:00Z","timestamp":1412380800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,10,4]],"date-time":"2014-10-04T00:00:00Z","timestamp":1412380800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,11,1]]},"abstract":"<jats:p>In the asymmetric unit of the title compound, [CrF<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)<jats:sub>4<\/jats:sub>][ZnCl<jats:sub>3<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)]\u00b7H<jats:sub>2<\/jats:sub>O, there are two independent complex cations, one trichlorido(pyridine-\u03ba<jats:italic>N<\/jats:italic>)zincate anion and one solvent water molecule. The cations lie on inversion centers. The Cr<jats:sup>III<\/jats:sup>ions are coordinated by four pyridine (py) N atoms in the equatorial plane and two F atoms in a<jats:italic>trans<\/jats:italic>axial arrangement, displaying a slightly distorted octahedral geometry. The Cr\u2014N(py) bond lengths are in the range 2.0873\u2005(14) to 2.0926\u2005(17)\u2005\u00c5 while the Cr\u2014F bond lengths are 1.8609\u2005(10) and 1.8645\u2005(10)\u2005\u00c5. The [ZnCl<jats:sub>3<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N)]<jats:sup>\u2212<\/jats:sup>anion has a distorted tetrahedral geometry. The Cl atoms of the anion were refined as disordered over two sets of sites in a 0.631\u2005(9):0.369\u2005(9) ratio. In the crystal, two anions and two water molecules are linked<jats:italic>via<\/jats:italic>O\u2014H...Cl hydrogen bonds, forming centrosymmetric aggregates. In addition, weak C\u2014H...Cl, C\u2014H...\u03c0 and \u03c0\u2013\u03c0 stacking interactions [centroid\u2013centroid distances = 3.712\u2005(2) and 3.780\u2005(2)\u00c5] link the components of the structure into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s160053681402145x","type":"journal-article","created":{"date-parts":[[2014,10,3]],"date-time":"2014-10-03T08:29:36Z","timestamp":1412324976000},"page":"290-293","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of<i>trans<\/i>-difluoridotetrakis(pyridine-\u03ba<i>N<\/i>)chromium(III) trichlorido(pyridine-\u03ba<i>N<\/i>)zincate monohydrate from synchrotron data"],"prefix":"10.1107","volume":"70","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,10,4]]},"reference":[{"key":"lh5726_bb2","unstructured":"Arvai, A. 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