{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:42Z","timestamp":1736831622265,"version":"3.33.0"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T00:00:00Z","timestamp":1414108800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T00:00:00Z","timestamp":1414108800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,11,1]]},"abstract":"<jats:p>The title solvated salt, C<jats:sub>29<\/jats:sub>H<jats:sub>41<\/jats:sub>N<jats:sub>2<\/jats:sub><jats:sup>+<\/jats:sup>\u00b7Br<jats:sup>\u2212<\/jats:sup>\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>was obtained from the reaction of the Arduengo-type carbene 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-4,5-dimethyl-2<jats:italic>H<\/jats:italic>-imidazol-2-ylidene with Si<jats:sub>2<\/jats:sub>Br<jats:sub>6<\/jats:sub>in dichloromethane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8\u2005(6)\u00b0; the dihedral angle between the benzene rings is 40.7\u2005(2)\u00b0. The anion also lies on the mirror plane and both dichloromethane molecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions<jats:italic>via<\/jats:italic>C\u2014H...Br hydrogen bonds.<\/jats:p>","DOI":"10.1107\/s1600536814023150","type":"journal-article","created":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T10:24:56Z","timestamp":1414146296000},"page":"o1193-o1194","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1<i>H<\/i>-imidazol-3-ium bromide dichloromethane disolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Matthias","family":"Berger","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Norbert","family":"Auner","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Bolte","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,10,24]]},"reference":[{"key":"hb7303_bb1","doi-asserted-by":"crossref","first-page":"11027","DOI":"10.1021\/ja00149a034","volume":"117","author":"Arduengo","year":"1995","journal-title":"J. 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