{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:43Z","timestamp":1736831623232,"version":"3.33.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2014,10,29]],"date-time":"2014-10-29T00:00:00Z","timestamp":1414540800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,10,29]],"date-time":"2014-10-29T00:00:00Z","timestamp":1414540800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,11,1]]},"abstract":"<jats:p>We report here the crystal structure of a ten-coordinate lanthanum(III) metal coordinated by five bidentate ethylenediamine ligands, [La(C<jats:sub>2<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>5<\/jats:sub>]Cl<jats:sub>3<\/jats:sub>\u00b7C<jats:sub>2<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>. One free ethylenediamine molecule and three Cl<jats:sup>\u2212<\/jats:sup>anions are also located in the asymmetric unit. The overall structure is held together by an extensive hydrogen-bonding network between the Cl<jats:sup>\u2212<\/jats:sup>anions and the NH groups on the metal-bound ethylenediamine ligands. The free ethylenediamine molecule is held in an ordered position by additional hydrogen bonds involving both the chlorides and \u2013NH groups on the metal-bound ligands. One highly disordered molecule of dichloromethane is located on an inversion center; however, all attempts to model this disorder were unsuccessful. The electron density in this space was removed using the BYPASS procedure [van der Sluis &amp; Spek (1990).<jats:italic>Acta Cryst.<\/jats:italic>A<jats:bold>46<\/jats:bold>, 194\u2013201].<\/jats:p>","DOI":"10.1107\/s1600536814023289","type":"journal-article","created":{"date-parts":[[2014,10,28]],"date-time":"2014-10-28T11:30:55Z","timestamp":1414495855000},"page":"424-426","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of pentakis(ethylenediamine-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)lanthanum(III) trichloride\u2013ethylenediamine\u2013dichloromethane (1\/1\/1)"],"prefix":"10.1107","volume":"70","author":[{"given":"Hope T.","family":"Sartain","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Richard J.","family":"Staples","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shannon M.","family":"Biros","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,10,29]]},"reference":[{"key":"pk2532_bb1","unstructured":"Bruker (2012). 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