{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:45:22Z","timestamp":1736844322362,"version":"3.33.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2014,11,5]],"date-time":"2014-11-05T00:00:00Z","timestamp":1415145600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,11,5]],"date-time":"2014-11-05T00:00:00Z","timestamp":1415145600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,12,15]]},"abstract":"<jats:p>The title compound, C<jats:sub>18<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>\u00b7CHCl<jats:sub>3<\/jats:sub>, crystallizes as a zwitterion. The C\u2014S bonds are almost equivalent, with lengths of 1.666\u2005(3) and 1.657\u2005(3)\u2005\u00c5. The S\u2014C\u2014S bond angle is expanded to 129.54\u2005(16)\u00b0 and the N\u2014C\u2014N angle is reduced to the tetrahedal value of 108.8\u2005(2)\u00b0. In the crystal, adjacent molecules are linked<jats:italic>via<\/jats:italic>C\u2014H...S hydrogen bonds, forming chains along [100]. The chloroform solvent molecule, which is disordered over two positions [occupancy ratio = 0.51\u2005(2):0.49\u2005(2)], is linked to the chain by bifurcated C\u2014H...(S,S) hydrogen bonds.<\/jats:p>","DOI":"10.1107\/s1600536814023800","type":"journal-article","created":{"date-parts":[[2014,11,4]],"date-time":"2014-11-04T09:32:45Z","timestamp":1415093565000},"page":"o1227-o1228","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of 1,3-dicyclohexyl-4,5-dimethyl-1<i>H<\/i>-imidazol-3-ium-2-carbodithioate chloroform monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Eyad","family":"Mallah","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kamal","family":"Sweidan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wael","family":"Abu Dayyih","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manfred","family":"Steimann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mahmoud","family":"Sunjuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,11,5]]},"reference":[{"key":"su5006_bb1","unstructured":"Enraf-Nonius (1998). 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