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Drastic changes in the bonding environment for lithium are demonstrated and this can be monitored using the position and intensity of the main Li<jats:italic>K<\/jats:italic>-absorption edge. The complex silicates confirm the assignment of the absorption edge to be a convolution of triply degenerate<jats:italic>p<\/jats:italic>-like states as previously proposed for simple lithium compounds. The Li<jats:italic>K<\/jats:italic>-edge position depends on the electronegativity of the element to which it is bound. The intensity of the first peak varies depending on the existence of a 2<jats:italic>p<\/jats:italic>electron and can be used to evaluate the degree of ionicity of the bond. The presence of a 2<jats:italic>p<\/jats:italic>electron results in a weak first-peak intensity. The maximum intensity of the absorption edge shifts to lower energy with increasing SiO<jats:sub>2<\/jats:sub>content for the lithium aluminosilicate minerals. The bond length distortion of the lithium aluminosilicates decreases with increasing SiO<jats:sub>2<\/jats:sub>content, thus increased distortion leads to an increase in edge energy which measures lithium's electron affinity.<\/jats:p>","DOI":"10.1107\/s1600577518000954","type":"journal-article","created":{"date-parts":[[2018,2,21]],"date-time":"2018-02-21T17:05:31Z","timestamp":1519232731000},"page":"543-551","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":14,"title":["A Li<i>K<\/i>-edge XANES study of salts and minerals"],"prefix":"10.1107","volume":"25","author":[{"given":"Cedrick","family":"O'Shaughnessy","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Grant S.","family":"Henderson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benjamin J. 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