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Cu<jats:sup>II<\/jats:sup>\n                  <jats:sub>5<\/jats:sub>(Te<jats:sup>IV<\/jats:sup>O<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(As<jats:sup>V<\/jats:sup>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> possesses a novel structure type including a new topological arrangement of Cu<jats:sup>II<\/jats:sup> and O atoms. Cu<jats:sup>II<\/jats:sup>\n                  <jats:sub>5<\/jats:sub>(Te<jats:sup>IV<\/jats:sup>O<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(As<jats:sup>V<\/jats:sup>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> is formed from a framework of two types of Jahn\u2013Teller distorted [Cu<jats:sup>II<\/jats:sup>O<jats:sub>6<\/jats:sub>] octahedra (one of which is considerably elongated) and [Cu<jats:sup>II<\/jats:sup>O<jats:sub>5<\/jats:sub>] square pyramids, which are linked by edge-sharing to form chains and dimers and by corner-sharing to complete a three-dimensional framework. [As<jats:sup>V<\/jats:sup>O<jats:sub>4<\/jats:sub>] tetrahedra and [Te<jats:sup>IV<\/jats:sup>O<jats:sub>5<\/jats:sub>] polyhedra bridge the edges of channels along the <jats:italic>a<\/jats:italic>-axis direction, with void space remaining for the Te<jats:sup>IV<\/jats:sup> stereoactive 5<jats:italic>s<\/jats:italic>\n                  <jats:sup>2<\/jats:sup> lone pairs. A comparison is made between the crystal structure of Cu<jats:sup>II<\/jats:sup>\n                  <jats:sub>5<\/jats:sub>(Te<jats:sup>IV<\/jats:sup>O<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(As<jats:sup>V<\/jats:sup>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> and those of known compounds and minerals, in particular fumarolitic Cu minerals.<\/jats:p>","DOI":"10.1107\/s2052520619014823","type":"journal-article","created":{"date-parts":[[2019,12,18]],"date-time":"2019-12-18T13:02:16Z","timestamp":1576674136000},"page":"1-6","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":7,"title":["The crystal structure of the first synthetic copper(II) tellurite arsenate, Cu<sup>II<\/sup>\n                  <sub>5<\/sub>(Te<sup>IV<\/sup>O<sub>3<\/sub>)<sub>2<\/sub>(As<sup>V<\/sup>O<sub>4<\/sub>)<sub>2<\/sub>"],"prefix":"10.1107","volume":"76","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2121-9971","authenticated-orcid":true,"given":"Owen P.","family":"Missen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5235-9910","authenticated-orcid":true,"given":"Matthias","family":"Weil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stuart J.","family":"Mills","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eugen","family":"Libowitzky","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,2,1]]},"reference":[{"key":"lo5063_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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