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Complex (1) was prepared via self-assembly of a copper(II) azamacrocyclic complex containing butyl pendant groups, [Cu(C<jats:sub>16<\/jats:sub>H<jats:sub>38<\/jats:sub>N<jats:sub>6<\/jats:sub>)(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>], with 2,7-naphthalenedicarboxylic acid. When monomeric compound (1) was immersed in CH<jats:sub>3<\/jats:sub>OH, coordination polymer (2) was obtained, indicating a solvent-triggered SCSC transformation. Furthermore, when (2) was immersed in water, an reverse SCSC transformation from (2) to (1) occurred. Complex (1) presents a 3D supramolecular structure formed via intermolecular hydrogen-bonding interactions, whereas complex (2) features a 1D zigzag coordination polymer. The reversible SCSC transformation of (1) and (2) was characterized using single-crystal X-ray diffraction and <jats:italic>in situ<\/jats:italic> powder X-ray diffraction techniques. Despite its poor porosity, complex (2) displayed interesting CO<jats:sub>2<\/jats:sub> adsorption behaviour under CO<jats:sub>2<\/jats:sub> gas.<\/jats:p>","DOI":"10.1107\/s2052520620002371","type":"journal-article","created":{"date-parts":[[2020,3,19]],"date-time":"2020-03-19T15:12:58Z","timestamp":1584630778000},"page":"225-232","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Solvent-triggered single-crystal-to-single-crystal transformation from a monomeric to polymeric copper(II) complex based on an aza macrocyclic ligand"],"prefix":"10.1107","volume":"76","author":[{"given":"Jong Won","family":"Shin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ah Rim","family":"Jeong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Younghak","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dae-Woong","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sang-Geul","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hyosun","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6903-0270","authenticated-orcid":true,"given":"Dohyun","family":"Moon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,3,19]]},"reference":[{"key":"rm5028_bb1","doi-asserted-by":"crossref","first-page":"4986","DOI":"10.1039\/C5SC01796C","volume":"6","author":"Aggarwal","year":"2015","journal-title":"Chem. 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