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The compounds have been characterized by powder X-ray diffraction, energy-dispersive spectroscopy, inductively coupled plasma mass spectrometry, scanning transmission electron microscopy, single crystal X-ray structure analysis, differential scanning calorimetry and thermogravimetry. The (MgO)<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>(Pr<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)<jats:italic><jats:sub>y<\/jats:sub><\/jats:italic>(MoO<jats:sub>3<\/jats:sub>)<jats:italic><jats:sub>z<\/jats:sub><\/jats:italic>(<jats:italic>x<\/jats:italic>+<jats:italic>y<\/jats:italic>+<jats:italic>z<\/jats:italic>= 1) solid solution series has been shown to extend to<jats:italic>x<\/jats:italic>= 0.03. The structure of the Mg-doped Pr<jats:sub>2<\/jats:sub>MoO<jats:sub>6<\/jats:sub>single crystals can be represented as superimposed lattices of the main matrix (Pr<jats:sub>2<\/jats:sub>MoO<jats:sub>6<\/jats:sub>) and lattices in which Mo atoms are partially replaced by Mg. The incorporation of Mg atoms into the structure of Pr<jats:sub>2<\/jats:sub>MoO<jats:sub>6<\/jats:sub>results in the disordering of the praseodymium and oxygen lattices. Both the polycrystalline and single-crystal Mg-doped samples are hygroscopic.<\/jats:p>","DOI":"10.1107\/s2052520620005740","type":"journal-article","created":{"date-parts":[[2020,5,22]],"date-time":"2020-05-22T10:37:15Z","timestamp":1590143835000},"page":"492-501","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":9,"title":["Synthesis, structure and properties of layered Pr<sub>2<\/sub>MoO<sub>6<\/sub>-based oxymolybdates doped with Mg"],"prefix":"10.1107","volume":"76","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3754-7862","authenticated-orcid":true,"given":"Valentina I.","family":"Voronkova","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8076-557X","authenticated-orcid":true,"given":"Alexander M.","family":"Antipin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timofei A.","family":"Sorokin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7744-9135","authenticated-orcid":true,"given":"Nataliya E.","family":"Novikova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elena P.","family":"Kharitonova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ekaterina I.","family":"Orlova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir B.","family":"Kvartalov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mikhail Yu.","family":"Presniakov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir I.","family":"Bondarenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7884-4180","authenticated-orcid":true,"given":"Alexander L.","family":"Vasiliev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9105-9272","authenticated-orcid":true,"given":"Nataliya I.","family":"Sorokina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2020,5,22]]},"reference":[{"key":"yb5024_bb1","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1134\/S1063774517040034","volume":"62","author":"Antipin","year":"2017","journal-title":"Crystallogr. 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