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They adopt the layered structure of the belousovite archetype, and constitute a morphotropic series. The apophyllite-type layers in these structures undergo different corrugations, most pronounced in the case of CsZn(SO\n                    <jats:sub>4<\/jats:sub>\n                    )I. In addition, during the study two species unrelated to belousovite, namely Na\n                    <jats:sub>4<\/jats:sub>\n                    Zn(SO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    and Cs\n                    <jats:sub>2<\/jats:sub>\n                    Cd\n                    <jats:sub>3<\/jats:sub>\n                    (SO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    , were found with framework crystal structures having different topology and belonging to new structure types.\n                  <\/jats:p>","DOI":"10.1107\/s2052520622003535","type":"journal-article","created":{"date-parts":[[2022,5,26]],"date-time":"2022-05-26T12:31:44Z","timestamp":1653568304000},"page":"499-509","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"special_numbering":"2","title":["Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability"],"prefix":"10.1107","volume":"78","author":[{"given":"Artem S.","family":"Borisov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1908-3152","authenticated-orcid":true,"given":"Oleg I.","family":"Siidra","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitri O.","family":"Charkin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Inorganic Chemistry, Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0444-0006","authenticated-orcid":true,"given":"Karim A.","family":"Zagidullin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Inorganic Chemistry, Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruslan K.","family":"Burshtynovich","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Inorganic Chemistry, Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalia S.","family":"Vlasenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,5,20]]},"reference":[{"key":"yh5019_bb1","doi-asserted-by":"crossref","first-page":"1280","DOI":"10.1016\/j.elecom.2011.08.023","volume":"13","author":"Ati","year":"2011","journal-title":"Electrochem. 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