{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T11:04:55Z","timestamp":1785409495227,"version":"3.56.0"},"reference-count":45,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2023,9,8]],"date-time":"2023-09-08T00:00:00Z","timestamp":1694131200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2023,9,8]],"date-time":"2023-09-08T00:00:00Z","timestamp":1694131200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci Cryst Eng Mater","Acta Crystallogr B","Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst B Struct Sci Cryst Eng Mater","Acta Cryst Sect B","Acta Cryst Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2023,8,1]]},"published-print":{"date-parts":[[2023,10,1]]},"abstract":"<jats:p>\n                    It is known that\n                    <jats:italic>N<\/jats:italic>\n                    -[4-(chlorobenzylidene)-4\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazol-4-amine in reaction with copper(I) perchlorate(VII) forms metastable breathing crystals built up of X-shaped binuclear units containing copper(I) ions in a trigonal coordination sphere. Using trifluoromethanesulfonate instead of perchlorate(VII) affects the self-assembly of the X-shaped units and the breathing function of the resulting crystals. The latter are not breathing crystals. Copper(I) trifluoromethanesulfonate with\n                    <jats:italic>N<\/jats:italic>\n                    -[4-(bromobenzylidene)-4\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazol-4-amine crystallizes in two forms: open (with the presence of 1D channels) and closed (without 1D channels). Both are characterized by the presence of X-shaped binuclear cationic units and the trigonal coordination sphere of copper(I) ions. The open form has the ability to engage in reversible sorption. The desorption process is associated with the large reorientation of the binuclear units and the reorganization of the intermolecular interactions leading to the closure of the channels. The post-synthetically obtained channel-less form differs from the channel-less form obtained by direct crystallization, the latter being incapable of sorption. The mechanism of the desorption process of the open form is governed by the general principle of dense packing, and the main reason for the sorption process is the formation of directional halogen\u2013halogen interactions. The halogen atom in the\n                    <jats:italic>para<\/jats:italic>\n                    position of the ligands influences the formation of different crystalline forms and also a different mechanism for the desorption process.\n                  <\/jats:p>","DOI":"10.1107\/s205252062300673x","type":"journal-article","created":{"date-parts":[[2023,8,17]],"date-time":"2023-08-17T10:46:22Z","timestamp":1692269182000},"page":"392-398","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Bromine versus chlorine substituent in breathing crystals of a copper(I) coordination compound with a triazolamine Schiff base"],"prefix":"10.1107","volume":"79","author":[{"given":"Emilia","family":"Ganczar","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00yae6e25","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agata","family":"Bia\u0142o\u0144ska","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00yae6e25","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,9,8]]},"reference":[{"key":"yv5011_bb1","doi-asserted-by":"crossref","first-page":"10641","DOI":"10.1021\/ja9715760","volume":"119","author":"Ashton","year":"1997","journal-title":"J. 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