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Dipodal ligands containing N-donor imidazole rings and a benzene ring as a spacer with different numbers of methyl substituents on the aromatic rings were selected for the study such as 1,3-bis(imidazol-1-ylmethyl)benzene (\n                    <jats:bold>L1<\/jats:bold>\n                    ), 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene (\n                    <jats:bold>L2<\/jats:bold>\n                    ), 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene (\n                    <jats:bold>L3<\/jats:bold>\n                    ), 1,3-bis(2-methylimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (\n                    <jats:bold>L4<\/jats:bold>\n                    ).\n                    <jats:bold>L4<\/jats:bold>\n                    has not been reported previously and was synthesized for this study. The formed metal complexes show the presence of polymeric (ligand with no or one methyl substituent;\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    ), or discrete motifs (3- or 5-methyl substituents;\n                    <jats:bold>5<\/jats:bold>\n                    \u2013\n                    <jats:bold>7<\/jats:bold>\n                    ). The new metal complexes\n                    <jats:bold>3<\/jats:bold>\n                    ,\n                    <jats:bold>5<\/jats:bold>\n                    and\n                    <jats:bold>6<\/jats:bold>\n                    were analyzed using single-crystal X-ray diffraction and powder diffraction. In addition, the structural analyses were supported by computational methods.\n                  <\/jats:p>","DOI":"10.1107\/s2052520623010260","type":"journal-article","created":{"date-parts":[[2023,12,20]],"date-time":"2023-12-20T13:42:04Z","timestamp":1703079724000},"page":"19-26","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Tailoring the dimensionality of metal complexes via ligand modifications"],"prefix":"10.1107","volume":"80","author":[{"given":"Paul","family":"Le Garff","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0102mm775","id-type":"ROR","asserted-by":"publisher"}],"department":["Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Renny","family":"Maria Losus","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0102mm775","id-type":"ROR","asserted-by":"publisher"}],"department":["Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simran","family":"Chaudhary","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0102mm775","id-type":"ROR","asserted-by":"publisher"}],"department":["Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2075-2122","authenticated-orcid":true,"given":"Liliana","family":"Dobrza\u0144ska","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0102mm775","id-type":"ROR","asserted-by":"publisher"}],"department":["Faculty of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,1,5]]},"reference":[{"key":"yv5014_bb1","doi-asserted-by":"crossref","first-page":"8957","DOI":"10.1039\/C5CE01348H","volume":"17","author":"Alen","year":"2015","journal-title":"CrystEngComm"},{"key":"yv5014_bb2","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1039\/D0CE01302A","volume":"23","author":"Arhangelskis","year":"2021","journal-title":"CrystEngComm"},{"key":"yv5014_bb3","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/j.jssc.2014.02.007","volume":"213","author":"Bisht","year":"2014","journal-title":"J. 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