{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T13:22:01Z","timestamp":1785417721868,"version":"3.56.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2024,3,19]],"date-time":"2024-03-19T00:00:00Z","timestamp":1710806400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2024,3,19]],"date-time":"2024-03-19T00:00:00Z","timestamp":1710806400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci Cryst Eng Mater","Acta Crystallogr B","Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst B Struct Sci Cryst Eng Mater","Acta Cryst Sect B","Acta Cryst Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2024,2,9]]},"published-print":{"date-parts":[[2024,4,1]]},"abstract":"\n The syntheses and structures of dimethyl [1\n 1<\/jats:sup>\n ,2\n 1<\/jats:sup>\n :2\n 4<\/jats:sup>\n ,3\n 1<\/jats:sup>\n -terphenyl]-1\n 4<\/jats:sup>\n ,3\n 4<\/jats:sup>\n -dicarboxylate (\n 1<\/jats:bold>\n ), dimethyl 2\n 2<\/jats:sup>\n ,2\n 5<\/jats:sup>\n -diiodo[1\n 1<\/jats:sup>\n ,2\n 1<\/jats:sup>\n :2\n 4<\/jats:sup>\n ,3\n 1<\/jats:sup>\n -terphenyl]-1\n 4<\/jats:sup>\n ,3\n 4<\/jats:sup>\n -dicarboxylate (\n 2<\/jats:bold>\n ), potassium [1\n 1<\/jats:sup>\n ,2\n 1<\/jats:sup>\n :2\n 4<\/jats:sup>\n ,3\n 1<\/jats:sup>\n -terphenyl]-1\n 4<\/jats:sup>\n ,3\n 4<\/jats:sup>\n -dicarboxylate (\n 3<\/jats:bold>\n ) and dimethyl [1,1\u2032-biphenyl]-4,4\u2032-dicarboxylate (\n 4<\/jats:bold>\n ) are reported. Neighboring phenyl rings in compounds\n 1<\/jats:bold>\n ,\n 3<\/jats:bold>\n and\n 4<\/jats:bold>\n have a planar structure (torsion angles are 0.6\u20134.1\u00b0) and the molecules are packed into regular layers. In the structure of the iodinated derivative of terphenyldicarboxylic acid (\n 2<\/jats:bold>\n ), the middle benzene ring of the terphenyl fragment is rotated relative to the other rings by 64\u00b0 due to the repulsion between the protons and the iodine atoms of neighboring rings. The formation of halogen bonds between iodine and oxygen atoms of the carbonyl group leads to the movement of molecules of one layer into another layer and the loss of layered structure. Potassium [1\n 1<\/jats:sup>\n ,2\n 1<\/jats:sup>\n :2\n 4<\/jats:sup>\n ,3\n 1<\/jats:sup>\n -terphenyl]-1\n 4<\/jats:sup>\n ,3\n 4<\/jats:sup>\n -dicarboxylate (\n 3<\/jats:bold>\n ) forms crystals with an ionic structure. The coordination number of the potassium cation is eight and the resulting coordination polyhedron is a distorted square antiprism. Dianions in the potassium salt crystal are packed in layers similar to the layers in the dimethyl ethers\n 1<\/jats:bold>\n and\n 4<\/jats:bold>\n . Salt\n 3<\/jats:bold>\n has high thermal stability to 500\u00b0C.\n <\/jats:p>","DOI":"10.1107\/s2052520624001318","type":"journal-article","created":{"date-parts":[[2024,2,26]],"date-time":"2024-02-26T12:05:12Z","timestamp":1708949112000},"page":"117-125","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Effect of a halogen bond on the crystal structure of terphenyldicarboxylic acid derivatives"],"prefix":"10.1107","volume":"80","author":[{"given":"Artyom A.","family":"Osipov","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Materials Science and Physical Chemistry of Materials"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey A.","family":"Nayfert","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Materials Science and Physical Chemistry of Materials"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6935-9711","authenticated-orcid":true,"given":"Sergey A.","family":"Sobalev","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Research laboratory `Multiscale modeling of multicomponent functional materials'"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kanthapazham","family":"Rajakumar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Scientific and Educational Center `Nanotechnologies'"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3368-9858","authenticated-orcid":true,"given":"Dmitry A.","family":"Zherebtsov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Materials Science and Physical Chemistry of Materials"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dar'ya V.","family":"Spiridonova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Denis A.","family":"Vinnik","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Materials Science and Physical Chemistry of Materials"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,3,19]]},"container-title":["Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/b\/issues\/2024\/02\/00\/aw5083\/aw5083.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/b\/issues\/2024\/02\/00\/aw5083\/aw5083.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T06:32:25Z","timestamp":1736749945000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2052520624001318"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,3,19]]},"references-count":0,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2024,4]]}},"alternative-id":["S2052520624001318"],"URL":"https:\/\/doi.org\/10.1107\/s2052520624001318","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2052520624001318\/aw5083sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2052520624001318\/aw50831sup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2052520624001318\/aw50832sup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2052520624001318\/aw50833sup4.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2052520624001318\/aw50834sup5.hkl","asserted-by":"subject"}]},"ISSN":["2052-5206"],"issn-type":[{"value":"2052-5206","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,3,19]]},"assertion":[{"value":"Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/b"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/b\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?aw5083","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 November 2023","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"9 February 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 March 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?aw5083"}},{"value":"\u00a9 Artyom A. Osipov\n et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}},{"value":"IUCr licence to publish","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/journals.iucr.org\/copyright\/licencetopublish.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}