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By employing a variety of crystallization solvents (polar protic, polar\/non-polar aprotic), a series of 12 crystalline solvatomorphs with the general formula [Cu(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>L<\/jats:italic>\n                    H)\n                    <jats:sub>4<\/jats:sub>\n                    ]\u00b7\n                    <jats:italic>x<\/jats:italic>\n                    (solvent) have been obtained [\n                    <jats:italic>L<\/jats:italic>\n                    H = 5-phenylimidazole,\n                    <jats:italic>x<\/jats:italic>\n                    (solvent) = 3.3(H\n                    <jats:sub>2<\/jats:sub>\n                    O) (\n                    <jats:bold>1<\/jats:bold>\n                    ), 2(methanol) (\n                    <jats:bold>2<\/jats:bold>\n                    ), 2(ethanol) (\n                    <jats:bold>3<\/jats:bold>\n                    ), 2(1-propanol) (\n                    <jats:bold>4<\/jats:bold>\n                    ), 2(2-propanol) (\n                    <jats:bold>5<\/jats:bold>\n                    ), 2(2-butanol) (\n                    <jats:bold>6<\/jats:bold>\n                    ), 2(dimethylformamide) (\n                    <jats:bold>7<\/jats:bold>\n                    ), 2(acetone) (\n                    <jats:bold>8<\/jats:bold>\n                    ), 2(tetrahydrofurane) (\n                    <jats:bold>9<\/jats:bold>\n                    ), 2(1,4-dioxane) (\n                    <jats:bold>10<\/jats:bold>\n                    ), 2(ethyl acetate) (\n                    <jats:bold>11<\/jats:bold>\n                    ) and 1(diethyl ether) (\n                    <jats:bold>12<\/jats:bold>\n                    )]. The structures have been solved using single-crystal X-ray diffraction and the complexes were characterized by thermal analysis and infrared spectroscopy. The solvatomorphs are isostructural (triclinic,\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    ), with the exception of compound\n                    <jats:bold>9<\/jats:bold>\n                    (monoclinic,\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    ). The supramolecular structures and the role of the various solvents is discussed. All potential hydrogen-bond functionalities, both of the [Cu(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>L<\/jats:italic>\n                    H)\n                    <jats:sub>4<\/jats:sub>\n                    ] units and of the solvents, are utilized in the course of the crystallization process. The supramolecular assembly in all structures is directed by strong recurring N\n                    <jats:sub>imidazole<\/jats:sub>\n                    \u2013H...O\n                    <jats:sub>perchlorate<\/jats:sub>\n                    motifs leading to robust scaffolds composed of the [Cu(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>L<\/jats:italic>\n                    H)\n                    <jats:sub>4<\/jats:sub>\n                    ] host complexes. The solvents are located in channels and, with the exception of the disordered waters in\n                    <jats:bold>1<\/jats:bold>\n                    and the diethyl ether in\n                    <jats:bold>12<\/jats:bold>\n                    , participate in hydrogen-bonding formation with the [Cu(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>L<\/jats:italic>\n                    H)\n                    <jats:sub>4<\/jats:sub>\n                    ] complexes, serving as both hydrogen-bond acceptors and donors (for the polar protic solvents in\n                    <jats:bold>2<\/jats:bold>\n                    \u2013\n                    <jats:bold>6<\/jats:bold>\n                    ), or solely as hydrogen-bond acceptors (for the polar\/non-polar aprotic solvents in\n                    <jats:bold>7<\/jats:bold>\n                    \u2013\n                    <jats:bold>11<\/jats:bold>\n                    ), linking the complexes and contributing to the stability of the crystalline compounds.\n                  <\/jats:p>","DOI":"10.1107\/s2052520624005948","type":"journal-article","created":{"date-parts":[[2024,7,15]],"date-time":"2024-07-15T08:18:40Z","timestamp":1721031520000},"page":"347-359","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Solvatomorphism in a series of copper(II) complexes with the 5-phenylimidazole\/perchlorate system as ligands"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9067-9499","authenticated-orcid":true,"given":"Edward","family":"Loukopoulos","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wvtq80","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5652-7747","authenticated-orcid":true,"given":"Constantina","family":"Papatriantafyllopoulou","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02qjrjx09","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6854-6785","authenticated-orcid":true,"given":"Eleni","family":"Moushi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02qjrjx09","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1431-3206","authenticated-orcid":true,"given":"Alexandros A.","family":"Kitos","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wvtq80","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4804-3822","authenticated-orcid":true,"given":"Anastasios J.","family":"Tasiopoulos","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02qjrjx09","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1792-6611","authenticated-orcid":true,"given":"Spyros P.","family":"Perlepes","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wvtq80","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4190-1342","authenticated-orcid":true,"given":"Vassilios","family":"Nastopoulos","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017wvtq80","id-type":"ROR","asserted-by":"publisher"}],"department":["Department of Chemistry"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,7,30]]},"reference":[{"key":"aw5090_bb1","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1039\/B919819A","volume":"12","author":"Aaker\u00f6y","year":"2010","journal-title":"CrystEngComm"},{"key":"aw5090_bb2","first-page":"435","volume":"27","author":"Altomare","year":"1994","journal-title":"J. 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