{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T13:35:59Z","timestamp":1785418559148,"version":"3.56.0"},"reference-count":64,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T00:00:00Z","timestamp":1734912000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T00:00:00Z","timestamp":1734912000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["23-22-00286"],"award-info":[{"award-number":["23-22-00286"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci Cryst Eng Mater","Acta Crystallogr B","Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst B Struct Sci Cryst Eng Mater","Acta Cryst Sect B","Acta Cryst Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2024,11,27]]},"published-print":{"date-parts":[[2025,2,1]]},"abstract":"<jats:p>\n                    The crystal structures and hyperfine magnetic parameters of EuFe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    and mixed Eu\n                    <jats:sub>0.82<\/jats:sub>\n                    La\n                    <jats:sub>0.18<\/jats:sub>\n                    Fe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    were studied over a wide temperature range in order to analyze correlations of the structural and magnetic features and the phase transitions in multiferroic compounds of the rare-earth iron borate family. The chemical compositions of the crystals are reported from X-ray fluorescence analysis. The crystal structures of EuFe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    and Eu\n                    <jats:sub>0.82<\/jats:sub>\n                    La\n                    <jats:sub>0.18<\/jats:sub>\n                    Fe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    were determined using single-crystal X-ray diffraction in the temperature range 25\u2013500\u2005K. A structural phase transition is observed in EuFe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    below 89\u2005K which is related to distortions in the interatomic distances and angles. The most significant of which are for\n                    <jats:italic>R<\/jats:italic>\n                    \u2014O,\n                    <jats:italic>R<\/jats:italic>\n                    \u2014B,\n                    <jats:italic>R<\/jats:italic>\n                    \u2014Fe, Fe\u2014O and Fe\u2014Fe distances, and the angles between the BO\n                    <jats:sub>3<\/jats:sub>\n                    triangles and the\n                    <jats:italic>ab<\/jats:italic>\n                    plane. There is no structural phase transition in lanthanum-doped EuFe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    based on specific heat measurements (2.2\u2013101.3\u2005K) and structure analysis (25\u2013500\u2005K), and the temperature dependences of the interatomic distances and angles are smooth. The lengths of the superexchange paths needed for the appearance of a structural phase transition in\n                    <jats:italic>R<\/jats:italic>\n                    Fe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    have been proposed. Negative thermal expansion is observed for both compounds below 90\u2005K, resulting from a growth of the interatomic Fe\u2014Fe distances in the iron chains during cooling. The largest atomic displacement parameters are observed for O atoms (O2), indicating that they have the highest mobility. The magnetic properties of EuFe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    and Eu\n                    <jats:sub>0.82<\/jats:sub>\n                    La\n                    <jats:sub>0.18<\/jats:sub>\n                    Fe\n                    <jats:sub>3<\/jats:sub>\n                    (BO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    were analyzed using M\u00f6ssbauer spectroscopy in the temperature range 4.5\u2013298\u2005K. N\u00e9el temperatures (\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>N<\/jats:sub>\n                    ) of 34.57\u2005(1) and 32.22\u2005(1)\u2005K are obtained based on M\u00f6ssbauer spectroscopy for the pure and doped crystals, respectively. The maximum specific heat capacity temperature dependence related to the magnetic phase transition for the doped crystal is observed at 31.2\u2005K. A violation of the strict arrangement of antiferromagnetic ordering in the\n                    <jats:italic>ab<\/jats:italic>\n                    plane in the La-doped crystals at low temperatures is suggested. The magnetic contributions of the two structural positions of the iron ions to the M\u00f6ssbauer spectra could not be distinguished in either pure and doped compounds, regardless of whether they are in the paramagnetic and antiferromagnetic regions.\n                  <\/jats:p>","DOI":"10.1107\/s2052520624011569","type":"journal-article","created":{"date-parts":[[2024,12,18]],"date-time":"2024-12-18T08:23:38Z","timestamp":1734510218000},"page":"69-83","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Structural and magnetic phase transitions in Eu\n                    <sub>\n                      1\u2013\n                      <i>x<\/i>\n                    <\/sub>\n                    La\n                    <sub>\n                      <i>x<\/i>\n                    <\/sub>\n                    Fe\n                    <sub>3<\/sub>\n                    (BO\n                    <sub>3<\/sub>\n                    )\n                    <sub>4<\/sub>\n                    (\n                    <i>x<\/i>\n                    \u00a0= 0, 0.18)"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0769-0246","authenticated-orcid":true,"given":"Ekaterina S.","family":"Smirnova","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6271-7902","authenticated-orcid":true,"given":"Kirill V.","family":"Frolov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ekaterina V.","family":"Sidorova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timofei A.","family":"Sorokin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9513-5084","authenticated-orcid":true,"given":"Olga A.","family":"Alekseeva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0826-5495","authenticated-orcid":true,"given":"Anton V.","family":"Guskov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pavel G.","family":"Gagarin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2653-8434","authenticated-orcid":true,"given":"Irina A.","family":"Gudim","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029bjdf19","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,12,23]]},"reference":[{"key":"yh5038_bb1","doi-asserted-by":"crossref","first-page":"1203","DOI":"10.3390\/cryst12091203","volume":"12","author":"Alekseeva","year":"2022","journal-title":"Crystals"},{"key":"yh5038_bb2","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1107\/S0567739474000337","volume":"30","author":"Becker","year":"1974","journal-title":"Acta Cryst. 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