{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T11:50:45Z","timestamp":1777463445505,"version":"3.51.4"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2014,1,17]],"date-time":"2014-01-17T00:00:00Z","timestamp":1389916800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,1,17]],"date-time":"2014-01-17T00:00:00Z","timestamp":1389916800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2014,2,1]]},"abstract":"<jats:p>The crystal structure of the tetranuclear organotin compound 1,1,3,3,5,5,7,7-octabutyl-7-((<jats:italic>E<\/jats:italic>)-2-cyano-3-{9-[2-(2-methoxyethoxy)ethyl]-9<jats:italic>H<\/jats:italic>-carbazol-3-yl}prop-2-enoyloxy)-4,8-dimethyl-2,4,6,8-tetroxa-1,3,5,7-tetrastannatricyclo[4.2.0.0<jats:sup>2,5<\/jats:sup>]oct-3-yl (<jats:italic>E<\/jats:italic>)-2-cyano-3-{9-[2-(2-methoxyethoxy)ethyl]-9<jats:italic>H<\/jats:italic>-carbazol-3-yl}prop-2-enoate, [Sn<jats:sub>4<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>)<jats:sub>8<\/jats:sub>(C<jats:sub>21<\/jats:sub>H<jats:sub>19<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(CH<jats:sub>3<\/jats:sub>O)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-O)<jats:sub>2<\/jats:sub>], consists of a core of three fused Sn<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>rings. The central ring consists of two Sn atoms each coordinated by two<jats:italic>n<\/jats:italic>-butyl chains, two \u03bc<jats:sub>3<\/jats:sub>-bridging O atoms and one \u03bc<jats:sub>2<\/jats:sub>-bridging methanolate O atom. The peripheral Sn<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>rings consist of one of the central ring Sn atoms, and an Sn coordinated by one \u03bc<jats:sub>3<\/jats:sub>-bridging O atom, one \u03bc<jats:sub>2<\/jats:sub>-bridging methanolate O atom, two<jats:italic>n<\/jats:italic>-butyl chains and the carboxylate O atom of a (<jats:italic>E<\/jats:italic>)-2-cyano-3-{9-[2-(2-methoxyethoxy)ethyl]-9<jats:italic>H<\/jats:italic>-carbazol-3-yl}prop-2-enoate ligand (<jats:italic>L<\/jats:italic>). Despite an apparent centrosymmetric nature, the complex does not crystallize about an inversion centre. The structure packs with \u03c0\u2013\u03c0 interactions between carbazole moieties on adjacent molecules.<\/jats:p>","DOI":"10.1107\/s2053229614000758","type":"journal-article","created":{"date-parts":[[2014,1,16]],"date-time":"2014-01-16T15:52:19Z","timestamp":1389887539000},"page":"185-188","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A tetranuclear organotin compound consisting of a core of three fused Sn<sub>2<\/sub>O<sub>2<\/sub>rings"],"prefix":"10.1107","volume":"70","author":[{"given":"Hui","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wen-Mo","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jie-Ying","family":"Wu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu-Peng","family":"Tian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,1,17]]},"reference":[{"key":"ov3040_bb1","unstructured":"Bruker (2002). 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Mater."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2014\/02\/00\/ov3040\/ov3040.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2014\/02\/00\/ov3040\/ov3040.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:32:34Z","timestamp":1736760754000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229614000758"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,1,17]]},"references-count":9,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2014,2]]}},"alternative-id":["S2053229614000758"],"URL":"https:\/\/doi.org\/10.1107\/s2053229614000758","relation":{},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014,1,17]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/c"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"24 August 2013","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 January 2014","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 January 2014","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ov3040"}},{"value":"\u00a9 2014 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}