{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T17:57:56Z","timestamp":1759514276474,"version":"3.33.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2014,4,10]],"date-time":"2014-04-10T00:00:00Z","timestamp":1397088000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,4,10]],"date-time":"2014-04-10T00:00:00Z","timestamp":1397088000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2014,3,25]]},"published-print":{"date-parts":[[2014,5,1]]},"abstract":"<jats:p>The crystal structure of the title compound {(C<jats:sub>5<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>[Cd<jats:sub>2<\/jats:sub>Cl<jats:sub>8<\/jats:sub>]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (I), consists of hydrogen-bonded 2-methylpiperazinediium (H<jats:sub>2<\/jats:sub>MPPA<jats:sup>2+<\/jats:sup>) cations in the presence of one-dimensional polymeric {[CdCl<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-Cl)]<jats:sup>2\u2212<\/jats:sup>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> anions. The Cd<jats:sup>II<\/jats:sup> centres are hexacoordinated by three terminal chlorides and three bridging chlorides and have a slightly distorted octahedral CdCl<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-Cl)<jats:sub>3<\/jats:sub> arrangement. The alternating CdCl<jats:sub>6<\/jats:sub> octahedra form four-membered Cd<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> rings by the sharing of neighbouring Cd\u2013Cl edges to give rise to extended one-dimensional ladder-like chains parallel to the <jats:italic>b<\/jats:italic> axis, with a Cd...Cd distance of 4.094\u2005(2)\u2005\u00c5 and a Cd...Cd...Cd angle of 91.264\u2005(8)\u00b0. The H<jats:sub>2<\/jats:sub>MPPA<jats:sup>2+<\/jats:sup> cations crosslink the [CdCl<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-Cl)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> chains by the formation of two N\u2014H...Cl hydrogen bonds to each chain, giving rise to one-dimensional ladder-like H<jats:sub>2<\/jats:sub>MPPA<jats:sup>2+<\/jats:sup>\u2013Cl<jats:sub>2<\/jats:sub> hydrogen-bonded chains [graph set <jats:italic>R<\/jats:italic>\n                  <jats:sub>4<\/jats:sub>\n                  <jats:sup>2<\/jats:sup>(14)]. The [CdCl<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-Cl)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> chains are interwoven with the H<jats:sub>2<\/jats:sub>MPPA<jats:sup>2+<\/jats:sup>\u2013Cl<jats:sub>2<\/jats:sub> hydrogen-bonded chains, giving rise to a three-dimensional supramolecular network.<\/jats:p>","DOI":"10.1107\/s205322961400655x","type":"journal-article","created":{"date-parts":[[2014,4,9]],"date-time":"2014-04-09T13:31:09Z","timestamp":1397050269000},"page":"445-448","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A one-dimensional ladder-like six-coordinate cadmium polymer: <i>catena<\/i>-poly[bis[(<i>S<\/i>)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-\u03bc<sub>3<\/sub>-chlorido]]"],"prefix":"10.1107","volume":"70","author":[{"given":"De-Hong","family":"Wu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,4,10]]},"reference":[{"key":"wq3059_bb1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/anie.199515551","volume":"34","author":"Bernstein","year":"1995","journal-title":"Angew. 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