{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:21:09Z","timestamp":1740172869558,"version":"3.37.3"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2014,4,30]],"date-time":"2014-04-30T00:00:00Z","timestamp":1398816000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,4,30]],"date-time":"2014-04-30T00:00:00Z","timestamp":1398816000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2014,4,21]]},"published-print":{"date-parts":[[2014,5,1]]},"abstract":"<jats:p>Two different one-dimensional supramolecular chains with Co<jats:sup>II<\/jats:sup> cations have been synthesized based on the semi-rigid ligand 2-[1-(pyridin-4-ylmethyl)-1<jats:italic>H<\/jats:italic>-benzimidazol-2-yl]quinoline (<jats:italic>L<\/jats:italic>), obtained by condensation of 2-(1<jats:italic>H<\/jats:italic>-benzimidazol-2-yl)quinoline and 4-(chloromethyl)pyridine hydrochloride. Starting from different Co<jats:sup>II<\/jats:sup> salts, two new compounds have been obtained, <jats:italic>viz. catena<\/jats:italic>-poly[[[dinitratocobalt(II)]-\u03bc-2-[1-(pyridin-4-ylmethyl)-1<jats:italic>H<\/jats:italic>-benzimidazol-2-yl]quinoline] dichloromethane monosolvate acetonitrile monosolvate], {[Co(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>4<\/jats:sub>)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>3<\/jats:sub>CN}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (I) and <jats:italic>catena<\/jats:italic>-poly[[[dichloridocobalt(II)]-\u03bc-2-[1-(pyridin-4-ylmethyl)-1<jats:italic>H<\/jats:italic>-benzimidazol-2-yl]quinoline] methanol disolvate], {[CoCl<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>4<\/jats:sub>)]\u00b72CH<jats:sub>3<\/jats:sub>OH}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (II). In (I), the Co<jats:sup>II<\/jats:sup> centres lie in a distorted octahedral [CoN<jats:sub>3<\/jats:sub>O<jats:sub>3<\/jats:sub>] coordination environment. {Co(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> units form one-dimensional helical chains, where the <jats:italic>L<\/jats:italic> ligand has different directions of twist. The helical chains stack together <jats:italic>via<\/jats:italic> interchain \u03c0\u2013\u03c0 interactions to form a two-dimensional sheet, and another type of \u03c0\u2013\u03c0 interaction further connects neighbouring sheets into a three-dimensional framework with hexagonal channels, in which the acetonitrile molecules and disordered dichloromethane molecules are located. In (II), the Co<jats:sup>II<\/jats:sup> centres lie in a distorted trigonal\u2013bipyramidal [CoCl<jats:sub>2<\/jats:sub>N<jats:sub>3<\/jats:sub>] coordination environment. {CoCl<jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> units form one-dimensional chains. The chains interact <jats:italic>via<\/jats:italic> C\u2014H...\u03c0 and C\u2014H...Cl interactions. The result is that two-dimensional sheets are generated, which are further linked into a three-dimensional framework <jats:italic>via<\/jats:italic> interlayer C\u2014H...Cl interactions. When viewed down the crystallographic <jats:italic>b<\/jats:italic> axis, the methanol solvent molecules are located in an orderly manner in wave-like channels.<\/jats:p>","DOI":"10.1107\/s2053229614009000","type":"journal-article","created":{"date-parts":[[2014,4,29]],"date-time":"2014-04-29T16:46:39Z","timestamp":1398789999000},"page":"522-527","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Two different one-dimensional supramolecular chains formed from the reaction of 2-[1-(pyridin-4-ylmethyl)-1<i>H<\/i>-benzimidazol-2-yl]quinoline with two different precursors, Co(NO<sub>3<\/sub>)<sub>2<\/sub> and CoCl<sub>2<\/sub>"],"prefix":"10.1107","volume":"70","author":[{"given":"Xiang-Wen","family":"Wu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dong","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-3307","authenticated-orcid":true,"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,4,30]]},"reference":[{"key":"bg3176_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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