{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:03Z","timestamp":1736831523711,"version":"3.33.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2014,4,30]],"date-time":"2014-04-30T00:00:00Z","timestamp":1398816000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,4,30]],"date-time":"2014-04-30T00:00:00Z","timestamp":1398816000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2014,4,22]]},"published-print":{"date-parts":[[2014,5,1]]},"abstract":"<jats:p>In poly[[\u03bc<jats:sub>3<\/jats:sub>-2,2\u2032-(disulfanediyl)dibenzoato-\u03ba<jats:sup>5<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>\u2032:<jats:italic>O<\/jats:italic>\u2032\u2032,<jats:italic>O<\/jats:italic>\u2032\u2032\u2032](1,10-phenanthroline-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032)cadmium(II)], [Cd(C<jats:sub>14<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>4<\/jats:sub>S<jats:sub>2<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, the asymmetric unit contains one Cd<jats:sup>II<\/jats:sup> cation, one 2,2\u2032-(disulfanediyl)dibenzoate anion (denoted dtdb<jats:sup>2\u2212<\/jats:sup>) and one 1,10-phenanthroline ligand (denoted phen). Each Cd<jats:sup>II<\/jats:sup> centre is seven-coordinated by five O atoms of bridging\/chelating carboxylate groups from three dtdb<jats:sup>2\u2212<\/jats:sup> ligands and by two N atoms from one phen ligand, forming a distorted pentagonal\u2013bipyramidal geometry. The Cd<jats:sup>II<\/jats:sup> cations are bridged by dtdb<jats:sup>2\u2212<\/jats:sup> anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture <jats:italic>via<\/jats:italic> a combination of aromatic C\u2014H...\u03c0 and \u03c0\u2013\u03c0 interactions. The thermogravimetric and luminescence properties of this compound were also investigated.<\/jats:p>","DOI":"10.1107\/s2053229614009036","type":"journal-article","created":{"date-parts":[[2014,4,29]],"date-time":"2014-04-29T16:46:39Z","timestamp":1398789999000},"page":"517-521","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["A two-dimensional Cd<sup>II<\/sup> coordination polymer with 2,2\u2032-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands"],"prefix":"10.1107","volume":"70","author":[{"given":"Yu-Xiu","family":"Jin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fang","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li-Min","family":"Yuan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chao-Guo","family":"Yan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wen-Long","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,4,30]]},"reference":[{"key":"bg3177_bb1","doi-asserted-by":"crossref","unstructured":"Blasse, G. & Grabmaier, B. 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