{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:24Z","timestamp":1736831544626,"version":"3.33.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2014,5,9]],"date-time":"2014-05-09T00:00:00Z","timestamp":1399593600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,5,9]],"date-time":"2014-05-09T00:00:00Z","timestamp":1399593600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2014,6,15]]},"abstract":"<jats:p>A novel quaternary mixed halogenide, Tl<jats:sub>5<\/jats:sub>Hg<jats:sub>2<\/jats:sub>Br<jats:sub>5<\/jats:sub>I<jats:sub>4<\/jats:sub>, was synthesized by fusion of thallium bromide and mercury iodide in a 5:2 molar ratio. The crystal structure of Tl<jats:sub>5<\/jats:sub>Hg<jats:sub>2<\/jats:sub>Br<jats:sub>5<\/jats:sub>I<jats:sub>4<\/jats:sub>represents a new series of composite structures described by the general formula<jats:italic>n<\/jats:italic>TlBr*<jats:italic>m<\/jats:italic>Tl<jats:sub>2<\/jats:sub>[HgBr<jats:sub>2<\/jats:sub>I<jats:sub>2<\/jats:sub>]; in this case,<jats:italic>n<\/jats:italic>= 4 and<jats:italic>m<\/jats:italic>= 8. Electronic structure calculations indicate that the title compound is a semiconductor.<\/jats:p>","DOI":"10.1107\/s2053229614009966","type":"journal-article","created":{"date-parts":[[2014,5,9]],"date-time":"2014-05-09T10:43:10Z","timestamp":1399632190000},"page":"550-554","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A new semiconducting quaternary mixed halogenide: pentathallium dimercury pentabromide tetraiodide, Tl<sub>5<\/sub>Hg<sub>2<\/sub>Br<sub>5<\/sub>I<sub>4<\/sub>"],"prefix":"10.1107","volume":"70","author":[{"given":"Volodymyr","family":"Pavlyuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Grygoriy","family":"Dmytriv","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Malgorzata","family":"Szyrej","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergii","family":"Levkovets","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oleh","family":"Parasyuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,5,9]]},"reference":[{"key":"yp3061_bb1","doi-asserted-by":"crossref","first-page":"3060","DOI":"10.1103\/PhysRevB.12.3060","volume":"12","author":"Andersen","year":"1975","journal-title":"Phys. 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