{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,18]],"date-time":"2026-04-18T21:43:21Z","timestamp":1776548601949,"version":"3.51.2"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2014,5,23]],"date-time":"2014-05-23T00:00:00Z","timestamp":1400803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,5,23]],"date-time":"2014-05-23T00:00:00Z","timestamp":1400803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2014,6,15]]},"abstract":"<jats:p>An organic\u2013inorganic hybrid compound,<jats:italic>catena<\/jats:italic>-poly[bis(3<jats:italic>H<\/jats:italic>-imidazol-1-ium) [[tetracyanido-\u03ba<jats:sup>4<\/jats:sup><jats:italic>C<\/jats:italic>-cobalt(III)]-\u03bc-cyanido-\u03ba<jats:sup>2<\/jats:sup><jats:italic>C<\/jats:italic>:<jats:italic>N<\/jats:italic>-[diaqualithium(I)]-\u03bc-cyanido-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>C<\/jats:italic>]], {(C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>[CoLi(CN)<jats:sub>6<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, was synthesized by the reaction of Li<jats:sub>3<\/jats:sub>[Co(CN)<jats:sub>6<\/jats:sub>] with imidazolium chloride in aqueous solution. The compound crystallizes in the monoclinic space group<jats:italic>C<\/jats:italic>2<jats:italic>\/c<\/jats:italic>(data collected at 273\u2005K). In the crystal structure, neighbouring [Co(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup>anionic units are linked by Li<jats:sup>+<\/jats:sup>cations through the cyanide groups in a<jats:italic>trans<\/jats:italic>mode, forming a one-dimensional zigzag chain structure extending along the<jats:italic>c<\/jats:italic>axis. A three-dimensional supramolecular network is formed through hydrogen-bonding interactions and is further stabilized by weak CN...\u03c0 interactions between the cyanide groups and the imidazolium cations.<\/jats:p>","DOI":"10.1107\/s2053229614011541","type":"journal-article","created":{"date-parts":[[2014,5,22]],"date-time":"2014-05-22T12:04:59Z","timestamp":1400760299000},"page":"603-605","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":7,"title":["An organic\u2013inorganic hybrid compound containing imidazolium cations and a one-dimensional lithium hexacyanidocobaltate-based anionic framework"],"prefix":"10.1107","volume":"70","author":[{"given":"Xiu-Dan","family":"Shao","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chun-Hua","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,5,23]]},"reference":[{"key":"wq3062_bb1","doi-asserted-by":"crossref","first-page":"7722","DOI":"10.1021\/ic060453q","volume":"45","author":"Atanasov","year":"2006","journal-title":"Inorg. 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