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Addition of 4,4\u2032-bipyridine to the synthesis afforded a two-dimensional extended structure, poly[[(\u03bc-4,4\u2032-bipyridine-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032)bis(\u03bc-diphenylphosphinato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>\u2032)cadmium(II)] dimethylformamide monosolvate], {[Cd(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>O<jats:sub>2<\/jats:sub>P)<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)]\u00b7C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (II). In (II), the 4,4\u2032-bipyridine molecules link the Cd<jats:sup>II<\/jats:sup>centers in the crystallographic<jats:italic>a<\/jats:italic>direction, while the phosphinate ligands link the Cd<jats:sup>II<\/jats:sup>centers in the crystallographic<jats:italic>b<\/jats:italic>direction to complete a two-dimensional sheet structure. Consideration of additional \u03c0\u2013\u03c0 interactions of the phenyl rings in (II) produces a three-dimensional structure with channels that encapsulate dimethylformamide molecules as solvent of crystallization. Both compounds were characterized by single-crystal X-ray diffraction and FT\u2013IR analysis.<\/jats:p>","DOI":"10.1107\/s2053229614022256","type":"journal-article","created":{"date-parts":[[2014,10,16]],"date-time":"2014-10-16T14:34:54Z","timestamp":1413470094000},"page":"1069-1074","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["One- and two-dimensional Cd<sup>II<\/sup>coordination polymers incorporating organophosphinate ligands"],"prefix":"10.1107","volume":"70","author":[{"given":"Jeffrey A.","family":"Rood","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Steven","family":"Boyer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Allen G.","family":"Oliver","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,10,17]]},"reference":[{"key":"yp3082_bb1","doi-asserted-by":"crossref","first-page":"7903","DOI":"10.1021\/ic300975s","volume":"51","author":"Al-Shboul","year":"2012","journal-title":"Inorg. 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