{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,17]],"date-time":"2026-03-17T20:56:43Z","timestamp":1773781003754,"version":"3.50.1"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T00:00:00Z","timestamp":1414108800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,10,24]],"date-time":"2014-10-24T00:00:00Z","timestamp":1414108800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2014,11,1]]},"abstract":"<jats:p>The title Cd<jats:sup>II<\/jats:sup>coordination framework, [Cd(C<jats:sub>15<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>5<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or [Cd(bpdc)(H<jats:sub>2<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>[H<jats:sub>2<\/jats:sub>bpdc is 2-(4-carboxybenzoyl)benzoic acid], has been prepared and characterized using IR spectroscopy, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Each Cd<jats:sup>II<\/jats:sup>centre is six-coordinated by two O atoms from one 2-(4-carboxylatobenzoyl)benzoate (bpdc<jats:sup>2\u2212<\/jats:sup>) ligand in chelating mode, three O-donor atoms from three other bpdc<jats:sup>2\u2212<\/jats:sup>anions and one O atom from a coordinated water molecule in an octahedral coordination environment. Two crystallographically equivalent Cd<jats:sup>II<\/jats:sup>cations are bridged by one O atom of the 2-carboxylate group of one bpdc<jats:sup>2\u2212<\/jats:sup>ligand and by both O atoms of the 4-carboxylate group of a second bpdc<jats:sup>2\u2212<\/jats:sup>ligand to form a binuclear [(Cd)<jats:sub>2<\/jats:sub>(O)(OCO)] secondary building unit. Adjacent secondary building units are interlinked to form a one-dimensional [Cd(OCO)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>chain. The bpdc<jats:sup>2\u2212<\/jats:sup>ligands link these rod-shaped chains to give rise to a complex two-dimensional [Cd(bpdc)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>framework with a 4,4-connected binodal net topology of point symbol {4<jats:sup>3<\/jats:sup>.6<jats:sup>2<\/jats:sup>.8}. The compound exhibits a strong fluorescence emission and typical ferroelectric behaviour in the solid state at room temperature.<\/jats:p>","DOI":"10.1107\/s2053229614022852","type":"journal-article","created":{"date-parts":[[2014,10,23]],"date-time":"2014-10-23T16:27:13Z","timestamp":1414081633000},"page":"1079-1082","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["A novel two-dimensional Cd<sup>II<\/sup>coordination polymer: poly[aqua[\u03bc<sub>4<\/sub>-2-(4-carboxylatobenzoyl)benzoato]cadmium(II)]"],"prefix":"10.1107","volume":"70","author":[{"given":"Hui-Ru","family":"Chen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wen-Wen","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,10,24]]},"reference":[{"key":"lg3147_bb1","doi-asserted-by":"crossref","first-page":"1088","DOI":"10.1039\/C1CS15055C","volume":"41","author":"Almeida Paz","year":"2012","journal-title":"Chem. 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