{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:43Z","timestamp":1736831623628,"version":"3.33.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2014,11,6]],"date-time":"2014-11-06T00:00:00Z","timestamp":1415232000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,11,6]],"date-time":"2014-11-06T00:00:00Z","timestamp":1415232000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2014,12,1]]},"abstract":"<jats:p>A twofold interpenetrating three-dimensional Cd<jats:sup>II<\/jats:sup>coordination framework, [Cd(C<jats:sub>8<\/jats:sub>H<jats:sub>3<\/jats:sub>NO<jats:sub>6<\/jats:sub>)(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, has been prepared and characterized by IR spectroscopy, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The asymmetric unit consists of a divalent Cd<jats:sup>II<\/jats:sup>atom, one 1,3-bis(2-methyl-1<jats:italic>H<\/jats:italic>-imidazol-1-yl)benzene (1,3-BMIB) ligand and one fully deprotonated 5-nitrobenzene-1,3-dicarboxylate (NO<jats:sub>2<\/jats:sub>-BDC<jats:sup>2\u2212<\/jats:sup>) ligand. The coordination sphere of the Cd<jats:sup>II<\/jats:sup>atom consists of five O-donor atoms from three different NO<jats:sub>2<\/jats:sub>-BDC<jats:sup>2\u2212<\/jats:sup>ligands and two imidazole N-donor atoms from two different 1,3-BMIB ligands, forming a distorted {CdN<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>} pentagonal bipyramid. The NO<jats:sub>2<\/jats:sub>-BDC ligand links three Cd<jats:sup>II<\/jats:sup>atoms<jats:italic>via<\/jats:italic>a \u03bc<jats:sub>1<\/jats:sub>-\u03b7<jats:sup>1<\/jats:sup>:\u03b7<jats:sup>1<\/jats:sup>chelating mode and a \u03bc<jats:sub>2<\/jats:sub>-\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>1<\/jats:sup>bridging mode. The title compound is a twofold interpenetrating 3,5-connected network with the {4<jats:sup>2<\/jats:sup>.6<jats:sup>5<\/jats:sup>.8<jats:sup>3<\/jats:sup>}{4<jats:sup>2<\/jats:sup>.6} topology. In addition, the compound exhibits fluorescence emissions in the solid state at room temperature.<\/jats:p>","DOI":"10.1107\/s2053229614024206","type":"journal-article","created":{"date-parts":[[2014,11,5]],"date-time":"2014-11-05T14:44:45Z","timestamp":1415198685000},"page":"1138-1142","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["A twofold interpenetrating three-dimensional Cd<sup>II<\/sup>coordination framework: poly[[\u03bc<sub>2<\/sub>-1,3-bis(2-methyl-1<i>H<\/i>-imidazol-1-yl)benzene](\u03bc<sub>3<\/sub>-5-nitrobenzene-1,3-dicarboxylato)cadmium(II)]"],"prefix":"10.1107","volume":"70","author":[{"given":"Le","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Qing","family":"Tao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,11,6]]},"reference":[{"key":"fg3328_bb1","doi-asserted-by":"crossref","first-page":"1330","DOI":"10.1039\/b802352m","volume":"38","author":"Allendorf","year":"2009","journal-title":"Chem. 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