{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,31]],"date-time":"2025-12-31T06:49:47Z","timestamp":1767163787106,"version":"build-2238731810"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2015,1,1]],"date-time":"2015-01-01T00:00:00Z","timestamp":1420070400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,1,1]],"date-time":"2015-01-01T00:00:00Z","timestamp":1420070400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,1,1]]},"abstract":"<jats:p>\n                    The title compound, (C\n                    <jats:sub>20<\/jats:sub>\n                    H\n                    <jats:sub>20<\/jats:sub>\n                    P)[Cd(C\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ], consists of ethyltriphenylphosphonium (EtPh\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sup>+<\/jats:sup>\n                    ) cations filling voids in a three-dimensional anionic cadmium dicyanamide network. In the structure, each Cd\n                    <jats:sup>II<\/jats:sup>\n                    atom is connected to six neighbouring Cd\n                    <jats:sup>II<\/jats:sup>\n                    atoms through six separate dicyanamide ligands, forming cube-shaped cages. The three-dimensional anionic network encloses a solvent-accessible void space of 1851\u2005\u00c5\n                    <jats:sup>3<\/jats:sup>\n                    , amounting to 69.3% of the unit-cell volume. Each cage accommodates only one EtPh\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sup>+<\/jats:sup>\n                    cation.\n                  <\/jats:p>","DOI":"10.1107\/s2053229614027090","type":"journal-article","created":{"date-parts":[[2014,12,12]],"date-time":"2014-12-12T07:22:39Z","timestamp":1418368959000},"page":"65-68","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":10,"title":["A three-dimensional anionic metal\u2013dicyanamide network in poly[ethyltriphenylphosphonium [tri-\u03bc\n                    <sub>2<\/sub>\n                    -dicyanamidato-cadmium(II)]]"],"prefix":"10.1107","volume":"71","author":[{"given":"Qiang","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,1,1]]},"reference":[{"key":"sk3571_bb1","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/S0010-8545(03)00119-X","volume":"246","author":"Batten","year":"2003","journal-title":"Coord. 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