{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,31]],"date-time":"2025-12-31T06:17:21Z","timestamp":1767161841859,"version":"build-2238731810"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2015,1,12]],"date-time":"2015-01-12T00:00:00Z","timestamp":1421020800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,1,12]],"date-time":"2015-01-12T00:00:00Z","timestamp":1421020800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,2,1]]},"abstract":"<jats:p>\n                    A new tetrazole\u2013metal supramolecular compound, di-\u03bc-chlorido-bis(trichlorido{1-[(1\n                    <jats:italic>H<\/jats:italic>\n                    -tetrazol-5-yl-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    )methyl]-1,4-diazoniabicyclo[2.2.2]octane}cadmium(II)), [Cd\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>16<\/jats:sub>\n                    N\n                    <jats:sub>6<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>8<\/jats:sub>\n                    ], has been synthesized and structurally characterized by single-crystal X-ray diffraction. In the structure, each Cd\n                    <jats:sup>II<\/jats:sup>\n                    cation is coordinated by five Cl atoms (two bridging and three terminal) and by one N atom from the 1-[(1\n                    <jats:italic>H<\/jats:italic>\n                    -tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand, adopting a slightly distorted octahedral coordination geometry. The bridging bicyclo[2.2.2]octane and chloride ligands link the Cd\n                    <jats:sup>II<\/jats:sup>\n                    cations into one-dimensional ribbon-like N\u2014H...Cl hydrogen-bonded chains along the\n                    <jats:italic>b<\/jats:italic>\n                    axis. An extensive hydrogen-bonding network formed by N\u2014H...Cl and C\u2014H...Cl hydrogen bonds, and interchain \u03c0\u2013\u03c0 stacking interactions between adjacent tetrazole rings, consolidate the crystal packing, linking the poymeric chains into a three-dimensional supramolecular network.\n                  <\/jats:p>","DOI":"10.1107\/s2053229614028009","type":"journal-article","created":{"date-parts":[[2015,1,9]],"date-time":"2015-01-09T12:02:26Z","timestamp":1420804946000},"page":"93-96","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["A new three-dimensional Cd\n                    <sup>II<\/sup>\n                    supramolecular framework constructed from the 1-[(1\n                    <i>H<\/i>\n                    -tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand"],"prefix":"10.1107","volume":"71","author":[{"given":"Qiang","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hui-Ting","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lin","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,1,12]]},"reference":[{"key":"lf3001_bb1","unstructured":"Brandenburg, K. & Putz, H. 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