{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:34Z","timestamp":1736831794013,"version":"3.33.0"},"reference-count":37,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2015,4,9]],"date-time":"2015-04-09T00:00:00Z","timestamp":1428537600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,4,9]],"date-time":"2015-04-09T00:00:00Z","timestamp":1428537600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,5,1]]},"abstract":"<jats:p>The title compound, [Cd<jats:sub>3<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>10<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>9<\/jats:sub>N<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or [Cd<jats:sub>3<\/jats:sub>(chdc)<jats:sub>3<\/jats:sub>(4-PyBIm)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, was synthesized hydrothermally from the reaction of Cd(CH<jats:sub>3<\/jats:sub>COO)<jats:sub>2<\/jats:sub>\u00b72H<jats:sub>2<\/jats:sub>O with 2-(pyridin-4-yl)-1<jats:italic>H<\/jats:italic>-benzimidazole (4-PyBIm) and cyclohexane-1,4-dicarboxylic acid (1,4-chdcH<jats:sub>2<\/jats:sub>). The asymmetric unit consists of one and a half Cd<jats:sup>II<\/jats:sup>cations, one 4-PyBIm ligand, one and a half 1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands and one coordinated water molecule. The central Cd<jats:sup>II<\/jats:sup>cation, located on an inversion centre, is coordinated by six carboxylate O atoms from six 1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands to complete an elongated octahedral coordination geometry. The two terminal rotationally symmetric Cd<jats:sup>II<\/jats:sup>cations each exhibits a distorted pentagonal\u2013bipyramidal geometry, coordinated by one N atom from 4-PyBIm, five O atoms from three 1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands and one O atom from an aqua ligand. The 1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands possess two conformations,<jats:italic>i.e.<\/jats:italic><jats:italic>e<\/jats:italic>,<jats:italic>e<\/jats:italic>-<jats:italic>trans<\/jats:italic>-chdc<jats:sup>2\u2212<\/jats:sup>and<jats:italic>e<\/jats:italic>,<jats:italic>a<\/jats:italic>-<jats:italic>cis<\/jats:italic>-chdc<jats:sup>2\u2212<\/jats:sup>. The<jats:italic>cis<\/jats:italic>-1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands bridge the Cd<jats:sup>II<\/jats:sup>cations to form a trinuclear {Cd<jats:sub>3<\/jats:sub>}-based chain along the<jats:italic>b<\/jats:italic>axis, while the<jats:italic>trans<\/jats:italic>-1,4-chdc<jats:sup>2\u2212<\/jats:sup>ligands further link adjacent one-dimensional chains to construct an interesting two-dimensional network.<\/jats:p>","DOI":"10.1107\/s2053229615005823","type":"journal-article","created":{"date-parts":[[2015,4,8]],"date-time":"2015-04-08T14:11:25Z","timestamp":1428502285000},"page":"369-373","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A novel two-dimensional cadmium(II) complex: poly[diaquatris(\u03bc<sub>4<\/sub>-cyclohexane-1,4-dicarboxylato)bis[2-(pyridin-4-yl)-1<i>H<\/i>-benzimidazole]tricadmium(II)"],"prefix":"10.1107","volume":"71","author":[{"given":"Xiu-Hong","family":"Yang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ming-Xing","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li-Juan","family":"Chen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing","family":"Guo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shen","family":"Lin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,4,9]]},"reference":[{"key":"ly3010_bb1","first-page":"2643","author":"Abed","year":"2014","journal-title":"Eur. 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