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Accordingly, the compound displays a pronounced preferred exopolyhedral ligand orientation (ELO) which is traced to both the greater<jats:italic>trans<\/jats:italic>influence of the cage B over the cage C atoms and the greater<jats:italic>trans<\/jats:italic>influence of the triphenylphosphane ligands over the nitrate ligand. The overall molecular architecture therefore agrees with that of a number of similar 3-<jats:italic>L<\/jats:italic>-3,3-<jats:italic>L<\/jats:italic>\u2032<jats:sub>2<\/jats:sub>-3,1,2-<jats:italic>closo<\/jats:italic>-<jats:italic>M<\/jats:italic>C<jats:sub>2<\/jats:sub>B<jats:sub>9<\/jats:sub>H<jats:sub>11<\/jats:sub>species in the literature.<\/jats:p>","DOI":"10.1107\/s2053229615008724","type":"journal-article","created":{"date-parts":[[2015,5,12]],"date-time":"2015-05-12T15:34:27Z","timestamp":1431444867000},"page":"461-464","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["The exopolyhedral ligand orientation (ELO) in 3-(nitrato-\u03ba<i>O<\/i>)-3,3-bis(triphenylphosphane-\u03ba<i>P<\/i>)-3-rhoda-1,2-dicarba-<i>closo<\/i>-dodecaborane(11) dichloromethane 2.2-solvate"],"prefix":"10.1107","volume":"71","author":[{"given":"Georgina M.","family":"Rosair","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Greig","family":"Scott","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alan J.","family":"Welch","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,5,13]]},"reference":[{"key":"fa3366_bb1","doi-asserted-by":"crossref","first-page":"3516","DOI":"10.1021\/om00007a059","volume":"14","author":"Anderson","year":"1995","journal-title":"Organometallics"},{"key":"fa3366_bb2","unstructured":"Bruker (2008). 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