{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T18:18:31Z","timestamp":1759515511906,"version":"3.32.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2015,6,13]],"date-time":"2015-06-13T00:00:00Z","timestamp":1434153600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,6,13]],"date-time":"2015-06-13T00:00:00Z","timestamp":1434153600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,7,1]]},"abstract":"<jats:p>The structures of five compounds consisting of (prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine complexed with copper in both the Cu<jats:sup>I<\/jats:sup>and Cu<jats:sup>II<\/jats:sup>oxidation states are presented, namely chlorido{(prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032}copper(I) 0.18-hydrate, [CuCl(C<jats:sub>15<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>3<\/jats:sub>)]\u00b70.18H<jats:sub>2<\/jats:sub>O, (1),<jats:italic>catena<\/jats:italic>-poly[[copper(I)-\u03bc<jats:sub>2<\/jats:sub>-(prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine-\u03ba<jats:sup>5<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032:<jats:italic>C<\/jats:italic><jats:sup>2<\/jats:sup>,<jats:italic>C<\/jats:italic><jats:sup>3<\/jats:sup>] perchlorate acetonitrile monosolvate], {[Cu(C<jats:sub>15<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>3<\/jats:sub>)]ClO<jats:sub>4<\/jats:sub>\u00b7CH<jats:sub>3<\/jats:sub>CN}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (2), dichlorido{(prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032}copper(II) dichloromethane monosolvate, [CuCl<jats:sub>2<\/jats:sub>(C<jats:sub>15<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>3<\/jats:sub>)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (3), chlorido{(prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032}copper(II) perchlorate, [CuCl(C<jats:sub>15<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>3<\/jats:sub>)]ClO<jats:sub>4<\/jats:sub>, (4), and di-\u03bc-chlorido-bis({(prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032}copper(II)) bis(tetraphenylborate), [Cu<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>(C<jats:sub>15<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>][(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>4<\/jats:sub>B]<jats:sub>2<\/jats:sub>, (5). Systematic variation of the anion from a coordinating chloride to a noncoordinating perchlorate for two Cu<jats:sup>I<\/jats:sup>complexes results in either a discrete molecular species, as in (1), or a one-dimensional chain structure, as in (2). In complex (1), there are two crystallographically independent molecules in the asymmetric unit. Complex (2) consists of the Cu<jats:sup>I<\/jats:sup>atom coordinated by the amine and pyridyl N atoms of one ligand and by the vinyl moiety of another unit related by the crystallographic screw axis, yielding a one-dimensional chain parallel to the crystallographic<jats:italic>b<\/jats:italic>axis. Three complexes with Cu<jats:sup>II<\/jats:sup>show that varying the anion composition from two chlorides, to a chloride and a perchlorate to a chloride and a tetraphenylborate results in discrete molecular species, as in (3) and (4), or a bridged bis-\u03bc-chlorido complex, as in (5). Complex (3) shows two strongly bound Cl atoms, while complex (4) has one strongly bound Cl atom and a weaker coordination by one perchlorate O atom. The large noncoordinating tetraphenylborate anion in complex (5) results in the core-bridged Cu<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>moiety.<\/jats:p>","DOI":"10.1107\/s2053229615010335","type":"journal-article","created":{"date-parts":[[2015,6,12]],"date-time":"2015-06-12T12:06:22Z","timestamp":1434110782000},"page":"526-533","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Structural studies of (prop-2-en-1-yl)bis[(pyridin-2-yl)methylidene]amine hetero-scorpionate copper complexes"],"prefix":"10.1107","volume":"71","author":[{"given":"Katherine A.","family":"Bussey","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Annie R.","family":"Cavalier","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jennifer R.","family":"Connell","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Margaret E.","family":"Mraz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kayode D.","family":"Oshin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tomislav","family":"Pintauer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Allen G.","family":"Oliver","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,6,13]]},"reference":[{"key":"sk3587_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"sk3587_bb2","doi-asserted-by":"crossref","first-page":"2046","DOI":"10.1021\/om801078c","volume":"28","author":"Bellott","year":"2009","journal-title":"Organometallics"},{"key":"sk3587_bb3","unstructured":"Bruker (2008). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"sk3587_bb4","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1016\/j.ica.2005.07.010","volume":"359","author":"Carvalho","year":"2006","journal-title":"Inorg. Chim. Acta"},{"key":"sk3587_bb5","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"sk3587_bb80","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/01614940903238759","volume":"52","author":"Eckenhoff","year":"2010","journal-title":"Catal. Rev."},{"key":"sk3587_bb6","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1107\/S0021889807059870","volume":"41","author":"Hooft","year":"2008","journal-title":"J. Appl. Cryst."},{"key":"sk3587_bb7","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"sk3587_bb8","doi-asserted-by":"crossref","first-page":"5424","DOI":"10.1021\/ic970541y","volume":"36","author":"Mandal","year":"1997","journal-title":"Inorg. Chem."},{"key":"sk3587_bb9","doi-asserted-by":"crossref","first-page":"506","DOI":"10.1021\/ed068p506","volume":"68","author":"Moog","year":"1991","journal-title":"J. Chem. Educ."},{"key":"sk3587_bb10","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"sk3587_bb11","doi-asserted-by":"crossref","first-page":"3525","DOI":"10.1021\/ic961369l","volume":"36","author":"Rodriguez","year":"1997","journal-title":"Inorg. Chem."},{"key":"sk3587_bb12","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"sk3587_bb13","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"sk3587_bb14","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"sk3587_bb15","doi-asserted-by":"crossref","first-page":"11065","DOI":"10.1021\/ja036172o","volume":"125","author":"Sullivan","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"sk3587_bb16","doi-asserted-by":"crossref","first-page":"3165","DOI":"10.1021\/ja00989a016","volume":"89","author":"Trofimenko","year":"1967","journal-title":"J. Am. Chem. Soc."},{"key":"sk3587_bb17","doi-asserted-by":"crossref","first-page":"6288","DOI":"10.1021\/ja01000a053","volume":"89","author":"Trofimenko","year":"1967","journal-title":"J. Am. Chem. Soc."},{"key":"sk3587_bb18","doi-asserted-by":"crossref","unstructured":"Trofimenko, S. (1999). In Scorpionates: The Coordination Chemistry of Poly(pyrazolyl)borate Ligands, 1st ed. London: Imperial College Press.","DOI":"10.1142\/p148"},{"key":"sk3587_bb19","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"sk3587_bb20","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","author":"Yang","year":"2007","journal-title":"Dalton Trans."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2015\/07\/00\/sk3587\/sk3587.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2015\/07\/00\/sk3587\/sk3587.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:39:53Z","timestamp":1736764793000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229615010335"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,6,13]]},"references-count":21,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2015,7]]}},"alternative-id":["S2053229615010335"],"URL":"https:\/\/doi.org\/10.1107\/s2053229615010335","relation":{},"ISSN":["2053-2296"],"issn-type":[{"type":"electronic","value":"2053-2296"}],"subject":[],"published":{"date-parts":[[2015,6,13]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?sk3587","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"17 April 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 May 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 June 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?sk3587"}},{"value":"\u00a9 2015 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}