{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:40:10Z","timestamp":1736768410085,"version":"3.32.0"},"reference-count":32,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2015,7,8]],"date-time":"2015-07-08T00:00:00Z","timestamp":1436313600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,7,8]],"date-time":"2015-07-08T00:00:00Z","timestamp":1436313600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,8,1]]},"abstract":"<jats:p>The Ugi four-component reaction, a powerful method for the synthesis of diverse dipeptide-like derivatives in combinatorial chemistry, was used to synthesize (<jats:italic>S<\/jats:italic>)-1\u2032-{<jats:italic>N<\/jats:italic>-[1-(anthracen-9-yl)-2-(<jats:italic>tert<\/jats:italic>-butylamino)-2-oxoethyl]-<jats:italic>N<\/jats:italic>-(4-methoxyphenyl)carbamoyl}ferrocene-1-carboxylic acid dichloromethane disolvate, [Fe(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>O<jats:sub>2<\/jats:sub>)(C<jats:sub>33<\/jats:sub>H<jats:sub>31<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (I), and (<jats:italic>S<\/jats:italic>)-2-(anthracen-9-yl)-<jats:italic>N<\/jats:italic>-<jats:italic>tert<\/jats:italic>-butyl-2-[<jats:italic>N<\/jats:italic>-(4-methylphenyl)ferrocenylformamido]acetamide, [Fe(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>)(C<jats:sub>33<\/jats:sub>H<jats:sub>31<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)], (II). They adopt broadly similar molecular conformations, with near-eclipsed cyclopentadienyl rings and near-perpendicular amide planes in their dipeptide-like chains, one of which is almost coplanar with its attached cyclopentadienyl ring but perpendicular to the aromatic ring bound to the N atom. In the supramolecular structure of (I), a two-dimensional network is constructed based on molecular dimers and a combination of intermolecular O\u2014H...O, N\u2014H...O and C\u2014H...O hydrogen bonds, forming<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(11),<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(16),<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(22) and<jats:italic>C<\/jats:italic>(9) motifs. These two-dimensional networks are connected by C\u2014H...O and C\u2014H...Cl contacts to create a three-dimensional framework, where one dichloromethane solvent molecule acts as a bridge between two neighbouring networks. In the packing of (II), classical hydrogen bonds are absent and an infinite one-dimensional chain is generated<jats:italic>via<\/jats:italic>a combination of C\u2014H...O hydrogen bonds and C\u2014H...\u03c0 interactions, producing a<jats:italic>C<\/jats:italic>(7) motif. This work describes a simple synthesis and the supramolecuar structures of ferrocenyl dipeptide-like compounds and is significant in the development of redox-active receptors.<\/jats:p>","DOI":"10.1107\/s2053229615012322","type":"journal-article","created":{"date-parts":[[2015,7,7]],"date-time":"2015-07-07T11:33:36Z","timestamp":1436268816000},"page":"667-672","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Two novel ferrocenyl dipeptide-like compounds generated<i>via<\/i>the Ugi four-component reaction"],"prefix":"10.1107","volume":"71","author":[{"given":"Guang-Kui","family":"Shao","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mei","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zheng","family":"Wei","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dian-Shun","family":"Guo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,7,8]]},"reference":[{"key":"ky3081_bb1","doi-asserted-by":"crossref","first-page":"2320","DOI":"10.1016\/j.jorganchem.2010.06.029","volume":"695","author":"Akbarzadeh","year":"2010","journal-title":"J. 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