{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T05:02:12Z","timestamp":1791090132688,"version":"4.1.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2015,7,15]],"date-time":"2015-07-15T00:00:00Z","timestamp":1436918400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,7,15]],"date-time":"2015-07-15T00:00:00Z","timestamp":1436918400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,8,1]]},"abstract":"<jats:p>Three coordination complexes with Cu<jats:sup>I<\/jats:sup>centres have been prepared using the symmetrical flexible organic ligands 1,3-bis{[5-(quinolin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propane (<jats:italic>L<\/jats:italic>1) and 1,4-bis{[5-(quinolin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}butane (<jats:italic>L<\/jats:italic>2). Crystallization of<jats:italic>L<\/jats:italic>1 with Cu(SO<jats:sub>3<\/jats:sub>CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>and of<jats:italic>L<\/jats:italic>2 with Cu(BF<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>and Cu(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>in a CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\/CH<jats:sub>3<\/jats:sub>OH mixed-solvent system at room temperature afforded the coordination complexes<jats:italic>catena<\/jats:italic>-poly[[copper(I)-\u03bc-1,3-bis{[5-(quinolin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propane] methanesulfonate dichloromethane 0.6-solvate], {[Cu(C<jats:sub>25<\/jats:sub>H<jats:sub>18<\/jats:sub>N<jats:sub>6<\/jats:sub>O<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)](CF<jats:sub>3<\/jats:sub>SO<jats:sub>3<\/jats:sub>)\u00b70.6CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (I), bis(\u03bc-1,4-bis{[5-(quinolin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}butane)dicopper(I) bis(tetrafluoridoborate)\u2013dichloromethane\u2013methanol (1\/1.5\/1), [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>26<\/jats:sub>H<jats:sub>20<\/jats:sub>N<jats:sub>6<\/jats:sub>O<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>](BF<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b71.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>3<\/jats:sub>OH, (II), and bis(\u03bc-1,4-bis{[5-(quinolin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}butane)dicopper(I) bis(perchlorate)\u2013dichloromethane\u2013methanol (1\/2\/1), [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>26<\/jats:sub>H<jats:sub>20<\/jats:sub>N<jats:sub>6<\/jats:sub>O<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>3<\/jats:sub>OH, (III). Under the control of the dumbbell-shaped CF<jats:sub>3<\/jats:sub>SO<jats:sub>3<\/jats:sub><jats:sup>\u2212<\/jats:sup>anion, complex (I) forms a one-dimensional chain and neighbouring chains form a spiral double chain. Under the control of the regular tetrahedron-shaped BF<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup>and ClO<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup>anions, complexes (II) and (III) have been obtained as bimetallic rings, which further interact<jats:italic>via<\/jats:italic>\u03c0\u2013\u03c0 interactions to form two-dimensional networks. The anions play a decisive role in determining the arrangement of these discrete molecular complexes in the solid state.<\/jats:p>","DOI":"10.1107\/s2053229615012929","type":"journal-article","created":{"date-parts":[[2015,7,14]],"date-time":"2015-07-14T15:26:35Z","timestamp":1436887595000},"page":"683-689","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Syntheses and structures of one Cu<sup>I<\/sup>-containing coordination polymer and two macrocyclic supramolecular complexes based on flexible 1,3,4-oxadiazole-containing ligands"],"prefix":"10.1107","volume":"71","author":[{"given":"Xiang-Wen","family":"Wu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wan-Fu","family":"Wu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shi","family":"Yin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2015,7,15]]},"reference":[{"key":"wq3091_bb1","unstructured":"Agilent (2013). 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