{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:08Z","timestamp":1736831828165,"version":"3.33.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2015,7,17]],"date-time":"2015-07-17T00:00:00Z","timestamp":1437091200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,7,17]],"date-time":"2015-07-17T00:00:00Z","timestamp":1437091200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,8,1]]},"abstract":"<jats:p>In the search for potential ferroelectric materials, molecular-based one-, two- and three-dimensional cadmium(II) organic\u2013inorganic compounds have been of interest as they often display solid\u2013solid phase transitions induced by a variation in temperature. A new cadmium dicyanamide complex, poly[4-dimethylamino-1-ethylpyridin-1-ium [tri-\u03bc-dicyanamido-\u03ba<jats:sup>6<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>1<\/jats:sup>:<jats:italic>N<\/jats:italic><jats:sup>5<\/jats:sup>-cadmium(II)]], {(C<jats:sub>9<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>2<\/jats:sub>)[Cd(C<jats:sub>2<\/jats:sub>N<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, was synthesized by the reaction of 4-dimethylamino-1-ethylpyridin-1-ium bromide, cadmium nitrate tetrahydrate and sodium dicyanamide in aqueous solution. In the crystal structure, each Cd<jats:sup>II<\/jats:sup>cation is octahedrally coordinated by six terminal N atoms from six anionic dicyanamide (dca) ligands. Neighbouring Cd<jats:sup>II<\/jats:sup>cations are linked together by dicyanamide bridges to form a two-dimensional coordination polymer. The organic cations are not involved in the formation of the supramolecular network.<\/jats:p>","DOI":"10.1107\/s2053229615013315","type":"journal-article","created":{"date-parts":[[2015,7,16]],"date-time":"2015-07-16T13:34:24Z","timestamp":1437053664000},"page":"717-720","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["A two-dimensional anionic Cd<sup>II<\/sup>polymer constructed through dicyanamide coordination bridges"],"prefix":"10.1107","volume":"71","author":[{"given":"Hui-Ting","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lin","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao-Li","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,7,17]]},"reference":[{"key":"yo3009_bb1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1071\/CH05315","volume":"59","author":"Biswas","year":"2006","journal-title":"Aust. 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