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The anionic framework is made up of disphenoidal [TeO<jats:sub>4<\/jats:sub>] polyhedra that are linked by corner-sharing to two neighbouring pyrovanadate units, resulting in chains of six-membered rings propagating parallel to [1\\overline{1}0]. The bridging O atom of the pyrovanadate unit is located on an inversion centre, leading to a staggered conformation and a linear V\u2014O\u2014V angle between the two [VO<jats:sub>4<\/jats:sub>] tetrahedra. The anionic chains are connected by interjacent six-coordinate Hg<jats:sup>2+<\/jats:sup>cations into a three-dimensional framework. The 5<jats:italic>s<\/jats:italic><jats:sup>2<\/jats:sup>lone electron pair of the Te<jats:sup>IV<\/jats:sup>atom is stereochemically active and protrudes into the free space of the chain links.<\/jats:p>","DOI":"10.1107\/s2053229615013406","type":"journal-article","created":{"date-parts":[[2015,7,14]],"date-time":"2015-07-14T15:26:35Z","timestamp":1436887595000},"page":"712-716","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A linear bridging angle in the pyrovanadate group within the crystal structure of Hg<sub>2<\/sub>V<sub>2<\/sub>Te<sub>2<\/sub>O<sub>11<\/sub>"],"prefix":"10.1107","volume":"71","author":[{"given":"Matthias","family":"Weil","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,7,15]]},"reference":[{"key":"ky3085_bb1","doi-asserted-by":"crossref","first-page":"2198","DOI":"10.1107\/S0567740880008382","volume":"36","author":"Baur","year":"1980","journal-title":"Acta Cryst. 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