{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:40:08Z","timestamp":1736768408815,"version":"3.32.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2015,8,27]],"date-time":"2015-08-27T00:00:00Z","timestamp":1440633600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2015,8,27]],"date-time":"2015-08-27T00:00:00Z","timestamp":1440633600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2015,9,1]]},"abstract":"<jats:p>The title Cd<jats:sup>II<\/jats:sup>compound, {[Cd<jats:sub>2<\/jats:sub>(C<jats:sub>13<\/jats:sub>H<jats:sub>7<\/jats:sub>NO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>4<\/jats:sub>]\u00b75H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, was synthesized by the hydrothermal reaction of Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O and 5-(pyridin-4-yl)isophthalic acid (H<jats:sub>2<\/jats:sub><jats:italic>L<\/jats:italic>). The asymmetric unit contains two crystallographically independent Cd<jats:sup>II<\/jats:sup>cations, two deprotonated<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands, four coordinated water molecules and five isolated water molecules. One of the Cd<jats:sup>II<\/jats:sup>cations adopts a six-coordinate octahedral coordination geometry involving three O atoms from one bidentate chelating and one monodentate carboxylate group of two different<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands, one N atom of another<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligand and two coordinated water molecules. The second Cd<jats:sup>II<\/jats:sup>cation adopts a seven-coordinate pentagonal\u2013bipyramidal coordination geometry involving four O atoms from two bidentate chelating carboxylate groups of two different<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands, one N atom of another<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligand and two coordinated water molecules. Each<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligand bridges three Cd<jats:sup>II<\/jats:sup>cations and, likewise, each Cd<jats:sup>II<\/jats:sup>cation connects to three<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands, giving rise to a two-dimensional graphite-like 6<jats:sup>3<\/jats:sup>layer structure. These two-dimensional layers are further linked by O\u2014H...O hydrogen-bonding interactions to form a three-dimensional supramolecular architecture. The photoluminescence properties of the title compound were also investigated.<\/jats:p>","DOI":"10.1107\/s2053229615015612","type":"journal-article","created":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T16:46:45Z","timestamp":1440607605000},"page":"834-838","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["A two-dimensional cadmium(II) coordination polymer based on 5-(pyridin-4-yl)isophthalic acid: poly[[tetraaquabis[\u03bc<sub>3<\/sub>-5-(pyridin-4-yl)isophthalato]dicadmium(II)] pentahydrate]"],"prefix":"10.1107","volume":"71","author":[{"given":"Fang","family":"Liu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing-Jing","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ming-Yuan","family":"Lei","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qing-Fu","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,8,27]]},"reference":[{"key":"ov3061_bb1","unstructured":"Bruker (2007). 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