{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:18:41Z","timestamp":1736831921225,"version":"3.33.0"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2016,10,5]],"date-time":"2016-10-05T00:00:00Z","timestamp":1475625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2016,10,5]],"date-time":"2016-10-05T00:00:00Z","timestamp":1475625600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2016,11,1]]},"abstract":"<jats:p>The reaction of a third generation tetratopic tris(pyrazolyl)methane ligand, namely 1,2,4,5-{[2,2,2-tris(1<jats:italic>H<\/jats:italic>-pyrazol-1-yl)ethoxy]methyl}benzene {1,2,4,5-C<jats:sub>6<\/jats:sub>H<jats:sub>2<\/jats:sub>[CH<jats:sub>2<\/jats:sub>OCH<jats:sub>2<\/jats:sub>C(pz)<jats:sub>3<\/jats:sub>]<jats:sub>4<\/jats:sub>,<jats:bold>L4<\/jats:bold>}, and [Cd<jats:sub>2<\/jats:sub>(thf)<jats:sub>5<\/jats:sub>](BF<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(thf is tetrahydrofuran) produces the coordination polymer<jats:italic>catena<\/jats:italic>-poly[[[bis[acetonitrilecadmium(II)]-\u03bc<jats:sub>4<\/jats:sub>-1,2,4,5-{[2,2,2-tris(1<jats:italic>H<\/jats:italic>-pyrazol-1-yl)ethoxy]methyl}benzene] tetrakis(tetrafluoroborate)]\u2013diethyl ether\u2013acetonitrile (1\/2\/2)], {[Cd<jats:sub>2<\/jats:sub>(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>2<\/jats:sub>(C<jats:sub>54<\/jats:sub>H<jats:sub>54<\/jats:sub>N<jats:sub>24<\/jats:sub>O<jats:sub>4<\/jats:sub>)](BF<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>\u00b72C<jats:sub>4<\/jats:sub>H<jats:sub>10<\/jats:sub>O\u00b72CH<jats:sub>3<\/jats:sub>CN}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>. The Cd<jats:sup>II<\/jats:sup>center is coordinated in a \u03ba<jats:sup>3<\/jats:sup>-fashion by one tris(pyrazolyl)methane group and in a \u03ba<jats:sup>2<\/jats:sup>\u2013\u03ba<jats:sup>0<\/jats:sup>fashion by another, while the sixth coordination site on the Cd<jats:sup>II<\/jats:sup>cation is occupied by an acetonitrile molecule. This bonding mode of the ligand generates an infinite one-dimensional structure built upon 32-atom metallomacrocycles connected by the C<jats:sub>6<\/jats:sub>H<jats:sub>2<\/jats:sub>spacer. This compound is isostructural with the silver(I) analogue of this ligand,<jats:italic>i.e.<\/jats:italic>{[Ag<jats:sub>2<\/jats:sub>(<jats:bold>L4<\/jats:bold>)](BF<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74CH<jats:sub>3<\/jats:sub>CN}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, thus showing the tendency of this system to form metal-based macrocyclic architectures.<\/jats:p>","DOI":"10.1107\/s205322961600783x","type":"journal-article","created":{"date-parts":[[2016,10,6]],"date-time":"2016-10-06T11:02:02Z","timestamp":1475751722000},"page":"832-837","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["A cadmium(II) coordination polymer formed from a third generation tetratopic tris(pyrazolyl)methane ligand"],"prefix":"10.1107","volume":"72","author":[{"given":"Radu F.","family":"Semeniuc","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel L.","family":"Reger","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark D.","family":"Smith","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,10,5]]},"reference":[{"key":"yp3121_bb1","unstructured":"Bruker (1998). 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