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However, no coordination compounds have been reported for the multifunctional amino-substituted sulfobenzoate ligand 2-amino-5-sulfobenzoic acid (H<jats:sub>2<\/jats:sub>asba). We expected that H<jats:sub>2<\/jats:sub>asba could be a suitable building block for the assembly of supramolecular networks due to its interesting structural characteristics. The reaction of cadmium(II) nitrate with H<jats:sub>2<\/jats:sub>asba in the presence of the auxiliary flexible dipyridylamide ligand<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis[(pyridin-4-yl)methyl]oxamide (4bpme) under ambient conditions formed a new mixed-ligand coordination compound, namely bis(3-amino-4-carboxybenzenesulfonato-\u03ba<jats:italic>O<\/jats:italic><jats:sup>1<\/jats:sup>)diaquabis{<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis[(pyridin-4-yl)methyl]oxamide-\u03ba<jats:italic>N<\/jats:italic>}cadmium(II)\u2013<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis[(pyridin-4-yl)methyl]oxamide\u2013water (1\/1\/4), [Cd(C<jats:sub>7<\/jats:sub>H<jats:sub>6<\/jats:sub>NO<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b7C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O, (1), which was characterized by single-crystal and powder X-ray diffraction analysis (PXRD), FT\u2013IR spectroscopy, thermogravimetric analysis (TG), and UV\u2013Vis and photoluminescence spectroscopic analyses in the solid state. The central Cd<jats:sup>II<\/jats:sup>atom in (1) occupies a special position on a centre of inversion and exhibits a slightly distorted octahedral geometry, being coordinated by two N atoms from two monodentate 4bpme ligands, four O atoms from two monodentate 4-amino-3-carboxybenzenesulfonate (Hasba<jats:sup>\u2212<\/jats:sup>) ligands and two coordinated water molecules. Interestingly, complex (1) further extends into a threefold polycatenated 0D\u21922D (0D is zero-dimensional and 2D is two-dimensional) interpenetrated supramolecular two-dimensional (4,4) layer through intermolecular hydrogen bonding. The interlayer hydrogen bonding further links adjacent threefold polycatenated two-dimensional layers into a three-dimensional network. The optical properties of complex (1) indicate that it may be used as a potential indirect band gap semiconductor material. Complex (1) exhibits an irreversible dehydration\u2013rehydration behaviour. The fluorescence properties have also been investigated in the solid state at room temperature.<\/jats:p>","DOI":"10.1107\/s2053229616016326","type":"journal-article","created":{"date-parts":[[2016,11,4]],"date-time":"2016-11-04T12:17:48Z","timestamp":1478261868000},"page":"939-946","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Synthesis and characterization of a cadmium(II)\u2013organic supramolecular coordination compound based on the multifunctional 2-amino-5-sulfobenzoic acid ligand"],"prefix":"10.1107","volume":"72","author":[{"given":"Gan-Yin","family":"Yuan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lei","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Meng-Jie","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kou-Lin","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2016,11,4]]},"reference":[{"key":"yf3111_bb1","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1080\/02603590903320833","volume":"30","author":"Baruah","year":"2009","journal-title":"Comments Inorg. 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