{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:21:20Z","timestamp":1740172880907,"version":"3.37.3"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2017,3,21]],"date-time":"2017-03-21T00:00:00Z","timestamp":1490054400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2017,3,21]],"date-time":"2017-03-21T00:00:00Z","timestamp":1490054400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"name":"National Science Centre, Poland","award":["2014\/15\/B\/ST8\/00101"],"award-info":[{"award-number":["2014\/15\/B\/ST8\/00101"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2017,4,1]]},"abstract":"<jats:p>Alloys from the ternary Li\u2013Al\u2013Sn system have been investigated with respect to possible applications as negative electrode materials in Li-ion batteries. This led to the discovery of a new ternary compound, a superstructure of the Li<jats:sub>13<\/jats:sub>Sn<jats:sub>5<\/jats:sub>binary compound. The ternary stannide, Li<jats:sub>9<\/jats:sub>Al<jats:sub>4<\/jats:sub>Sn<jats:sub>5<\/jats:sub>(nonalithium tetraaluminium pentastannide; trigonal,<jats:italic>P<\/jats:italic>\\overline{3}<jats:italic>m<\/jats:italic>1,<jats:italic>hP18<\/jats:italic>), crystallizes as a new structure type, which is an ordered variant of the binary Li<jats:sub>13<\/jats:sub>Sn<jats:sub>5<\/jats:sub>structure type. One Li and one Sn site have \\overline{3}<jats:italic>m<\/jats:italic>. symmetry, and all other atoms occupy sites of 3<jats:italic>m<\/jats:italic>. symmetry. The polyhedra around all types of atoms are rhombic dodecahedra. The electronic structure was calculated by the tight-binding linear muffin-tin orbital atomic spheres approximation method. The electron concentration is higher around the Sn and Al atoms, which form an [Al<jats:sub>4<\/jats:sub>Sn<jats:sub>5<\/jats:sub>]<jats:sup><jats:italic>m\u2212<\/jats:italic><\/jats:sup>polyanion.<\/jats:p>","DOI":"10.1107\/s205322961700420x","type":"journal-article","created":{"date-parts":[[2017,3,21]],"date-time":"2017-03-21T18:09:35Z","timestamp":1490119775000},"page":"337-342","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Li<sub>9<\/sub>Al<sub>4<\/sub>Sn<sub>5<\/sub>as a new ordered superstructure of the Li<sub>13<\/sub>Sn<sub>5<\/sub>type"],"prefix":"10.1107","volume":"73","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1893-2706","authenticated-orcid":true,"given":"Volodymyr","family":"Pavlyuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Grygoriy","family":"Dmytriv","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ivan","family":"Tarasiuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Helmut","family":"Ehrenberg","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,3,21]]},"reference":[{"key":"yo3033_bb1","doi-asserted-by":"crossref","first-page":"3060","DOI":"10.1103\/PhysRevB.12.3060","volume":"12","author":"Andersen","year":"1975","journal-title":"Phys. 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