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Fluorous coordination compounds exhibit several advantageous properties, such as enhanced high thermal and oxidative stability, low polarity, weak intermolecular interactions and a small surface tension compared to hydrocarbons. C\u2014H...F\u2014C interactions, although weak, play a significant role in regulating the arrangement of the organic molecules in the crystalline state and stabilizing the secondary structure. Two cadmium(II) fluorous coordination compounds formed from 2,2\u2032-bipyridine, 4,4\u2032-bipyridine and pentafluorobenzoate ligands, namely <jats:italic>catena<\/jats:italic>-poly[[aqua(2,2\u2032-bipyridine-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032)(2,3,4,5,6-pentafluorobenzoato-\u03ba<jats:italic>O<\/jats:italic>)cadmium(II)]-\u03bc-2,3,4,5,6-pentafluorobenzoato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>\u2032], [Cd(C<jats:sub>7<\/jats:sub>F<jats:sub>5<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (1), and <jats:italic>catena<\/jats:italic>-poly[[diaquabis(2,3,4,5,6-pentafluorobenzoato-\u03ba<jats:italic>O<\/jats:italic>)cadmium(II)]-\u03bc-4,4\u2032-bipyridine-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032], [Cd(C<jats:sub>7<\/jats:sub>F<jats:sub>5<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (2), have been synthesized solvothermally and structurally characterized. Compound (1) shows a one-dimensional chain structure composed of Cd\u2014O coordination bonds and is stabilized by \u03c0\u2013\u03c0 stacking and O\u2014H...O hydrogen-bond interactions. Compound (2) displays a one-dimensional linear chain structure formed by Cd\u2014N coordination interactions involving the 4,4\u2032-bipyridine ligand. Adjacent one-dimensional chains are extended into two-dimensional sheets by O\u2014H...O hydrogen bonds between the coordinated water molecules and adjacent carboxylate groups. Moreover, the chains are further linked by C\u2014H...F\u2014C interactions to afford a three-dimensional network. In both structures, hydrogen bonding involving the coordinated water molecules is a primary driving force in the formation of the supramolecular structures.<\/jats:p>","DOI":"10.1107\/s2053229617006003","type":"journal-article","created":{"date-parts":[[2017,4,26]],"date-time":"2017-04-26T11:26:48Z","timestamp":1493206008000},"page":"424-429","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Two cadmium(II) fluorous coordination compounds tuned by different bipyridines"],"prefix":"10.1107","volume":"73","author":[{"given":"Ya-Jie","family":"Kong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li-Juan","family":"Han","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lu-Tong","family":"Fan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng-Peng","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuang","family":"Yin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,4,26]]},"reference":[{"key":"ov3088_bb1","first-page":"7405","volume":"105","author":"Ansgar","year":"2011","journal-title":"J. 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