{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T13:43:55Z","timestamp":1789998235641,"version":"4.0.1"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T00:00:00Z","timestamp":1508803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T00:00:00Z","timestamp":1508803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"name":"National Science Centre, Poland","award":["2014\/15\/B\/ST8\/00101"],"award-info":[{"award-number":["2014\/15\/B\/ST8\/00101"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2017,10,18]]},"published-print":{"date-parts":[[2017,11,1]]},"abstract":"<jats:p>Li\u2013B\u2013C alloys have attracted much interest because of their potential use in lithium-ion batteries and superconducting materials. The formation of the new compound LiBC<jats:sub>3<\/jats:sub> [lithium boron tricarbide; own structure type, space group <jats:italic>P<\/jats:italic>\\overline{6}<jats:italic>m<\/jats:italic>2, <jats:italic>a<\/jats:italic> = 2.5408\u2005(3)\u2005\u00c5 and <jats:italic>c<\/jats:italic> = 7.5989\u2005(9)\u2005\u00c5] has been revealed and belongs to the graphite-like structure family. The crystal structure of LiBC<jats:sub>3<\/jats:sub> presents hexagonal graphene carbon networks, lithium layers and heterographene B\/C networks, alternating sequentially along the <jats:italic>c<\/jats:italic> axis. According to electronic structure calculations using the tight-binding linear muffin-tin orbital-atomic spheres approximations (TB\u2013LMTO\u2013ASA) method, strong covalent B\u2014C and C\u2014C interactions are established. The coordination polyhedra for the B and C atoms are trigonal prisms and for the Li atoms are hexagonal prisms.<\/jats:p>","DOI":"10.1107\/s2053229617015182","type":"journal-article","created":{"date-parts":[[2017,10,24]],"date-time":"2017-10-24T14:35:39Z","timestamp":1508855739000},"page":"984-989","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["LiBC<sub>3<\/sub>: a new borocarbide based on graphene and heterographene networks"],"prefix":"10.1107","volume":"73","author":[{"given":"Viktoria","family":"Milashius","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1893-2706","authenticated-orcid":true,"given":"Volodymyr","family":"Pavlyuk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Karolina","family":"Kluziak","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Grygoriy","family":"Dmytriv","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Helmut","family":"Ehrenberg","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2017,10,24]]},"reference":[{"key":"yo3041_bb1","doi-asserted-by":"crossref","first-page":"3060","DOI":"10.1103\/PhysRevB.12.3060","volume":"12","author":"Andersen","year":"1975","journal-title":"Phys. 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