{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:32:17Z","timestamp":1785889937523,"version":"3.56.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,9]],"date-time":"2017-11-09T00:00:00Z","timestamp":1510185600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2017,11,9]],"date-time":"2017-11-09T00:00:00Z","timestamp":1510185600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21301060"],"award-info":[{"award-number":["21301060"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"crossref","award":["2017J01084"],"award-info":[{"award-number":["2017J01084"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry"},{"name":"Program for New Century Excellent Talents in Fujian Province University","award":["2014FJ-NCET-ZR02"],"award-info":[{"award-number":["2014FJ-NCET-ZR02"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2017,10,30]]},"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>Mixed-valence copper(I\/II) atoms have been introduced successfully into a Pb\/I skeleton to obtain two heterometallic iodoplumbates, namely poly[bis(tetra-<jats:italic>n<\/jats:italic>-butylammonium) [bis(\u03bc<jats:sub>3<\/jats:sub>-dimethyldithiocarbamato)dodeca-\u03bc<jats:sub>3<\/jats:sub>-iodido-hexa-\u03bc<jats:sub>2<\/jats:sub>-iodido-tetracopper(I)copper(II)hexalead(II)]], {(C<jats:sub>16<\/jats:sub>H<jats:sub>36<\/jats:sub>N)<jats:sub>2<\/jats:sub>[Cu<jats:sub>4<\/jats:sub>\n                  <jats:sup>I<\/jats:sup>Cu<jats:sup>II<\/jats:sup>Pb<jats:sub>6<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>I<jats:sub>18<\/jats:sub>]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (I), and poly[[\u03bc<jats:sub>3<\/jats:sub>-iodido-tri-\u03bc<jats:sub>2<\/jats:sub>-iodido-iodido[bis(1,10-phenanthroline)copper(I)]copper(I)copper(II)lead(II)] hemiiodine], {[Cu<jats:sup>I<\/jats:sup>Cu<jats:sup>II<\/jats:sup>PbI<jats:sub>5<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b70.5I<jats:sub>2<\/jats:sub>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (II), under solution and solvothermal conditions, respectively. Compound (I) contains two-dimensional anionic layers, which are built upon the linkages of Cu<jats:sup>II<\/jats:sup>(S<jats:sub>2<\/jats:sub>CNMe<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub> units and one-dimensional anionic Pb\/I\/Cu<jats:sup>I<\/jats:sup> chains. Tetra-<jats:italic>n<\/jats:italic>-butylammonium cations are located between the anionic layers and connected to them <jats:italic>via<\/jats:italic> C\u2014H...I hydrogen-bonding interactions. Compound (II) exhibits a one-dimensional neutral structure, which is composed of [PbI<jats:sub>5<\/jats:sub>] square pyramids, [Cu<jats:sup>I<\/jats:sup>I<jats:sub>4<\/jats:sub>] tetrahedra and [Cu<jats:sup>II<\/jats:sup>N<jats:sub>4<\/jats:sub>I] trigonal bipyramids. Face-to-face aromatic \u03c0\u2013\u03c0 stacking interactions between adjacent 1,10-phenanthroline ligands stabilize the structure and assemble compound (II) into a three-dimensional supramolecular structure. I<jats:sub>2<\/jats:sub> molecules lie in the voids of the structure.<\/jats:p>","DOI":"10.1107\/s2053229617015807","type":"journal-article","created":{"date-parts":[[2017,11,9]],"date-time":"2017-11-09T14:55:59Z","timestamp":1510239359000},"page":"1098-1103","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Syntheses and crystal structures of two heterometallic iodoplumbates containing mixed-valence copper(I\/II)"],"prefix":"10.1107","volume":"73","author":[{"given":"Le-Qing","family":"Fan","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Tong","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2017,11,9]]},"reference":[{"key":"ov3096_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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