{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:40:19Z","timestamp":1736768419858,"version":"3.32.0"},"reference-count":32,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2017,11,24]],"date-time":"2017-11-24T00:00:00Z","timestamp":1511481600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2017,11,24]],"date-time":"2017-11-24T00:00:00Z","timestamp":1511481600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2017,11,15]]},"published-print":{"date-parts":[[2017,12,1]]},"abstract":"<jats:p>A monomeric Pd<jats:sup>II<\/jats:sup> complex bearing a mixed carbocyclic\/N-heterocyclic carbene ligand and two bromides was reacted with an excess of elemental iodine, which resulted in the surprising removal of one bromide ligand and dimerization of the mixed-carbene complex to form di-\u03bc-bromido-bis{[1-(cyclohepta-2,4,6-trien-2-yl-1-ylidene-\u03ba<jats:italic>C<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>)-3-(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II)} bis(pentaiodide) dichloromethane monosolvate, [Pd<jats:sub>2<\/jats:sub>Br<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>](I<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>. The dimeric complex features a slightly distorted square-planar core of two Pd<jats:sup>II<\/jats:sup> centres bridged by two bromide ligands, which lie in the same plane as the seven- and five-membered rings of the bidentate carbene ligand. The counter-ions in the single crystal were found to be pentaiodide monoanions featuring their typical V-shape, whereas for the bulk material, a mixture of Br\/I interhalides is proposed.<\/jats:p>","DOI":"10.1107\/s2053229617016412","type":"journal-article","created":{"date-parts":[[2017,11,24]],"date-time":"2017-11-24T15:32:57Z","timestamp":1511537577000},"page":"1131-1136","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Dimerization of a mixed-carbene Pd<sup>II<\/sup> dibromide complex by elemental iodine"],"prefix":"10.1107","volume":"73","author":[{"given":"Christian","family":"Jandl","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"P\u00f6thig","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2017,11,24]]},"reference":[{"key":"ov3101_bb1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1107\/S0021889804003528","volume":"37","author":"Allen","year":"2004","journal-title":"J. Appl. Cryst."},{"key":"ov3101_bb2","unstructured":"Bruker (2014). SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ov3101_bb3","unstructured":"Bruker (2015). APEX3. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ov3101_bb4","doi-asserted-by":"crossref","first-page":"3491","DOI":"10.1002\/ejic.200500146","author":"Chaviara","year":"2005","journal-title":"Eur. J. Inorg. Chem."},{"key":"ov3101_bb5","doi-asserted-by":"crossref","first-page":"6940","DOI":"10.1002\/anie.201001865","volume":"49","author":"Dr\u00f6ge","year":"2010","journal-title":"Angew. Chem. Int. Ed."},{"key":"ov3101_bb6","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"ov3101_bb7","doi-asserted-by":"crossref","first-page":"3166","DOI":"10.1002\/ange.200703883","volume":"120","author":"Hahn","year":"2008","journal-title":"Angew. Chem."},{"key":"ov3101_bb8","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1002\/zaac.201400085","volume":"640","author":"Haller","year":"2014","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ov3101_bb9","doi-asserted-by":"crossref","first-page":"16526","DOI":"10.1039\/C6DT03303B","volume":"45","author":"Hausmann","year":"2016","journal-title":"Dalton Trans."},{"key":"ov3101_bb10","doi-asserted-by":"crossref","first-page":"1342","DOI":"10.1002\/1521-3757(20020415)114:8<1342::AID-ANGE1342>3.0.CO;2-A","volume":"114","author":"Herrmann","year":"2002","journal-title":"Angew. Chem."},{"key":"ov3101_bb11","doi-asserted-by":"crossref","first-page":"2162","DOI":"10.1002\/anie.199721621","volume":"36","author":"Herrmann","year":"1997","journal-title":"Angew. Chem. Int. Ed."},{"key":"ov3101_bb12","doi-asserted-by":"crossref","first-page":"3859","DOI":"10.1002\/anie.200503589","volume":"45","author":"Herrmann","year":"2006","journal-title":"Angew. Chem. Int. Ed."},{"key":"ov3101_bb13","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1038\/nature13384","volume":"510","author":"Hopkinson","year":"2014","journal-title":"Nature"},{"key":"ov3101_bb14","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1107\/S0021889811043202","volume":"44","author":"H\u00fcbschle","year":"2011","journal-title":"J. Appl. Cryst."},{"key":"ov3101_bb15","doi-asserted-by":"crossref","first-page":"6398","DOI":"10.1021\/om500738d","volume":"33","author":"Jandl","year":"2014","journal-title":"Organometallics"},{"key":"ov3101_bb16","doi-asserted-by":"crossref","first-page":"2098","DOI":"10.1039\/C6CC08468K","volume":"53","author":"Jandl","year":"2017","journal-title":"Chem. Commun."},{"key":"ov3101_bb17","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1021\/cg201170w","volume":"12","author":"Johnson","year":"2012","journal-title":"Cryst. Growth Des."},{"key":"ov3101_bb18","doi-asserted-by":"crossref","first-page":"2058","DOI":"10.1002\/ejic.201700034","author":"Lee","year":"2017","journal-title":"Eur. J. Inorg. Chem."},{"key":"ov3101_bb19","doi-asserted-by":"crossref","first-page":"5099","DOI":"10.1021\/acs.organomet.5b00692","volume":"34","author":"Luy","year":"2015","journal-title":"Organometallics"},{"key":"ov3101_bb20","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Cryst."},{"key":"ov3101_bb21","doi-asserted-by":"crossref","first-page":"244","DOI":"10.1002\/chem.201604392","volume":"23","author":"Mann","year":"2017","journal-title":"Chem. Eur. J."},{"key":"ov3101_bb22","doi-asserted-by":"crossref","first-page":"8249","DOI":"10.1021\/om300867g","volume":"31","author":"Mantas-\u00d6ktem","year":"2012","journal-title":"Organometallics"},{"key":"ov3101_bb23","doi-asserted-by":"crossref","first-page":"3408","DOI":"10.1021\/cr800516g","volume":"109","author":"\u00d6fele","year":"2009","journal-title":"Chem. Rev."},{"key":"ov3101_bb24","doi-asserted-by":"crossref","first-page":"3211","DOI":"10.1021\/ic502792q","volume":"54","author":"Reineke","year":"2015","journal-title":"Inorg. Chem."},{"key":"ov3101_bb25","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ov3101_bb26","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ov3101_bb27","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"ov3101_bb28","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1107\/S2053229614024929","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ov3101_bb29","doi-asserted-by":"crossref","first-page":"1649","DOI":"10.1021\/cr0204101","volume":"103","author":"Svensson","year":"2003","journal-title":"Chem. Rev."},{"key":"ov3101_bb30","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1107\/S0021889810000452","volume":"43","author":"Thomas","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"ov3101_bb31","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"ov3101_bb32","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","author":"Yang","year":"2007","journal-title":"Dalton Trans."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2017\/12\/00\/ov3101\/ov3101.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2017\/12\/00\/ov3101\/ov3101.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:30:17Z","timestamp":1736764217000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229617016412"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,11,24]]},"references-count":32,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2017,12]]}},"alternative-id":["S2053229617016412"],"URL":"https:\/\/doi.org\/10.1107\/s2053229617016412","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229617016412\/ov3101sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229617016412\/ov3101Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229617016412\/ov3101Isup3.cdx","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"type":"electronic","value":"2053-2296"}],"subject":[],"published":{"date-parts":[[2017,11,24]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?ov3101","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"26 September 2017","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"15 November 2017","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 November 2017","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ov3101"}},{"value":"\u00a9 2017 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}