{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,13]],"date-time":"2026-01-13T08:46:56Z","timestamp":1768294016662,"version":"3.49.0"},"reference-count":38,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T00:00:00Z","timestamp":1515715200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T00:00:00Z","timestamp":1515715200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2017,12,30]]},"published-print":{"date-parts":[[2018,2,1]]},"abstract":"<jats:p>Guanidine is the functional group on the side chain of arginine, one of the fundamental building blocks of life. In recent years, a number of compounds based on the aminoguanidine (AG) moiety have been described as presenting high anticancer activities. The product of condensation between two molecules of AG and one molecule of formaldehyde was isolated in the protonated form as the dinitrate salt (systematic name: 2,8-diamino-1,3,4,6,7,9-hexaazanona-1,8-diene-1,9-diium dinitrate), C<jats:sub>3<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>8<\/jats:sub>\n                  <jats:sup>2+<\/jats:sup>\u00b72NO<jats:sub>3<\/jats:sub>\n                  <jats:sup>\u2212<\/jats:sup>, (I). The cation lacks crystallographically imposed symmetry and comprises two terminal planar guanidinium groups, which share an N\u2014C\u2014N unit. Each cation in (I) builds 14 N\u2014H...O hydrogen bonds and is separated from adjacent cations by seven nitrate anions. The AG self-condensation reaction in the presence of copper(II) chloride and chloride anions led to the formation of the organic\u2013inorganic hybrid 1,2-bis(diaminomethylidene)hydrazine-1,2-diium tetrachloridocuprate(II), (C<jats:sub>2<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>6<\/jats:sub>)[CuCl<jats:sub>4<\/jats:sub>], (II). Its asymmetric unit is composed of half a diprotonated 1,2-bis(diaminomethylidene)hydrazine-1,2-diium dication and half a tetrachloridocuprate(II) dianion, with the Cu<jats:sup>II<\/jats:sup> atom situated on a twofold rotation axis. The planar guanidinium fragments in (II) have their planes twisted by approximately 77.64\u2005(5)\u00b0 with respect to each other. The tetrahedral [CuCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion is severely distorted and its pronounced `planarity' must originate from its involvement in multiple N\u2014H...Cl hydrogen bonds. It was reported that [CuCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anions, with a <jats:italic>trans<\/jats:italic>-Cl\u2014Cu\u2014Cl angle (\u0398) of \u223c140\u00b0, are yellow\u2013green at room temperature, with the colour shifting to a deeper green as \u0398 increases and toward orange as \u0398 decreases. Brown salt (II), with a \u0398 value of 142.059\u2005(8)\u00b0, does not fit the trend, which emphasizes the need to take other structural factors into consideration. In the crystal of salt (II), layers of cations and anions alternate along the <jats:italic>b<\/jats:italic> axis, with the minimum Cu...Cu distance being 7.5408\u2005(3)\u2005\u00c5 inside a layer. The structures of salts (I) and (II) were substantiated <jats:italic>via<\/jats:italic> spectroscopic data. The endothermic reaction involved in the thermal decomposition of (I) requires additional oxygen. The title salts may be useful for the screening of new substances with biological activity.<\/jats:p>","DOI":"10.1107\/s2053229617018514","type":"journal-article","created":{"date-parts":[[2018,1,12]],"date-time":"2018-01-12T14:36:45Z","timestamp":1515767805000},"page":"152-158","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Formaldehyde\u2013aminoguanidine condensation and aminoguanidine self-condensation products: syntheses, crystal structures and characterization"],"prefix":"10.1107","volume":"74","author":[{"given":"Elena A.","family":"Buvaylo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1834-3020","authenticated-orcid":true,"given":"Vladimir N.","family":"Kokozay","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nataliia Yu.","family":"Strutynska","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4315-8399","authenticated-orcid":true,"given":"Olga Yu.","family":"Vassilyeva","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1515-6636","authenticated-orcid":true,"given":"Brian W.","family":"Skelton","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,1,12]]},"reference":[{"key":"jx3005_bb1","unstructured":"Agilent (2014). 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