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The pendant carboxylic acid, sulfonic acid and amino groups could not only play a role in directing bonding but could also have the potential to act as hydrogen-bond donors and acceptors, resulting in extended high-dimensional supramolecular networks. Two new Cu<jats:sup>II<\/jats:sup>coordination compounds, namely<jats:italic>catena<\/jats:italic>-poly[[[diaquacopper(II)]-\u03bc-1,6-bis(1<jats:italic>H<\/jats:italic>-1,2,4-triazol-1-yl)hexane-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>4<\/jats:sup>:<jats:italic>N<\/jats:italic><jats:sup>4\u2032<\/jats:sup>] bis(3-amino-4-carboxybenzenesulfonate) dihydrate], {[Cu(C<jats:sub>10<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>](C<jats:sub>7<\/jats:sub>H<jats:sub>6<\/jats:sub>NO<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>\u00b72H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or {[Cu(bth)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>](Hafsb)<jats:sub>2<\/jats:sub>\u00b72H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (1), and bis(\u03bc-2-amino-5-sulfonatobenzoato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic><jats:sup>1<\/jats:sup>:<jats:italic>O<\/jats:italic><jats:sup>1\u2032<\/jats:sup>)bis{\u03bc-1,2-bis[(1<jats:italic>H<\/jats:italic>-imidazol-1-yl)methyl]benzene-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>3<\/jats:sup>:<jats:italic>N<\/jats:italic><jats:sup>3\u2032<\/jats:sup>}bis[aquacopper(II)] trihydrate, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>5<\/jats:sub>NO<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b73H<jats:sub>2<\/jats:sub>O or [Cu<jats:sub>2<\/jats:sub>(afsb)<jats:sub>2<\/jats:sub>(obix)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b73H<jats:sub>2<\/jats:sub>O, (2), have been obtained through the assembly between H<jats:sub>2<\/jats:sub>afsb and the Cu<jats:sup>II<\/jats:sup>ion in the presence of the flexible N-donor ligands 1,6-bis(1<jats:italic>H<\/jats:italic>-1,2,4-triazol-1-yl)hexane (bth) and 1,2-bis[(1<jats:italic>H<\/jats:italic>-1,2,4-triazol-1-yl)methyl]benzene (obix), respectively. Compound (1) consists of a cationic coordination polymeric chain and 3-amino-4-carboxybenzenesulfonate (Hafsb<jats:sup>\u2212<\/jats:sup>) anions. Compound (2) exhibits an asymmetric dinuclear structure. There are hydrogen-bonded networks within the lattices of (1) and (2). Interestingly, both (1) and (2) exhibit reversible dehydration\u2013rehydration behaviour.<\/jats:p>","DOI":"10.1107\/s2053229618002474","type":"journal-article","created":{"date-parts":[[2018,2,21]],"date-time":"2018-02-21T15:54:29Z","timestamp":1519228469000},"page":"332-341","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["A new copper(II) supramolecular coordination polymer and a dinuclear compound with multifunctional 2-amino-5-sulfobenzoic acid and flexible N-donor ligands: synthesis, structure and characterization"],"prefix":"10.1107","volume":"74","author":[{"given":"Peng-Cheng","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kou-Lin","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,2,21]]},"reference":[{"key":"ov3107_bb1","doi-asserted-by":"crossref","first-page":"66","DOI":"10.1016\/j.inoche.2016.10.027","volume":"74","author":"Alm\u00e1\u0161i","year":"2016","journal-title":"Inorg. 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