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Two new coordination polymers, namely poly[[\u03bc-<jats:italic>trans<\/jats:italic>-1-(2-aminopyridin-3-yl)-2-(pyridin-4-yl)ethene-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032](\u03bc<jats:sub>3<\/jats:sub>-5-methylisophthalato-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>O<\/jats:italic>\n                  <jats:sup>1\u2032<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>3\u2032<\/jats:sup>)cadmium(II)], [Cd(C<jats:sub>9<\/jats:sub>H<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>3<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Cd(5-Me-ip)(2-NH<jats:sub>2<\/jats:sub>-3,4-bpe)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (<jats:bold>I<\/jats:bold>), and poly[[\u03bc-<jats:italic>trans<\/jats:italic>-1-(2-aminopyridin-3-yl)-2-(pyridin-4-yl)ethene-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032](\u03bc<jats:sub>2<\/jats:sub>-5-hydroxyisophthalato-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>O<\/jats:italic>\n                  <jats:sup>1\u2032<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>5<\/jats:sup>)cadmium(II)], [Cd(C<jats:sub>8<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>5<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>3<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Cd(5-HO-ip)(2-NH<jats:sub>2<\/jats:sub>-3,4-bpe)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (<jats:bold>II<\/jats:bold>), have been prepared hydrothermally by the self-assembly of Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O and <jats:italic>trans<\/jats:italic>-1-(2-aminopyridin-3-yl)-2-(pyridin-4-yl)ethene (2-NH<jats:sub>2<\/jats:sub>-3,4-bpe) with two similar dicarboxylic acids, <jats:italic>i.e.<\/jats:italic> 5-methylisophthalic acid (5-Me-H<jats:sub>2<\/jats:sub>ip) and 5-hydroxyisophthalic acid (5-HO-H<jats:sub>2<\/jats:sub>ip). The coordination network of (<jats:bold>I<\/jats:bold>) is a two-dimensional <jats:bold>sql<\/jats:bold> net parallel to (101). Adjacent <jats:bold>sql<\/jats:bold> nets are further linked to form a three-dimensional supramolecular framework <jats:italic>via<\/jats:italic> hydrogen-bonding interactions. Compound (<jats:bold>II<\/jats:bold>) is a two-dimensional (3,5)-connected coordination network parallel to (010) with the point symbol (6<jats:sup>3<\/jats:sup>)(5<jats:sup>5<\/jats:sup>6<jats:sup>4<\/jats:sup>7). As the other reactants and reaction conditions are the same, the structural differences between (<jats:bold>I<\/jats:bold>) and (<jats:bold>II<\/jats:bold>) are undoubtedly determined by the different substituent groups in the 5-position of isophthalic acid. Both (<jats:bold>I<\/jats:bold>) and (<jats:bold>II<\/jats:bold>) exhibit good thermal stabilities and photoluminescence properties.<\/jats:p>","DOI":"10.1107\/s2053229618009312","type":"journal-article","created":{"date-parts":[[2018,7,6]],"date-time":"2018-07-06T12:37:21Z","timestamp":1530880641000},"page":"894-900","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Substituent effects of two isophthalate derivatives on the construction of cadmium coordination polymers incorporating a dipyridyl ligand"],"prefix":"10.1107","volume":"74","author":[{"given":"Lin","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qian-Kun","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yun","family":"Xu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ni-Ya","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,7,6]]},"reference":[{"key":"sk3696_bb1","doi-asserted-by":"crossref","first-page":"1475","DOI":"10.1002\/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO;2-3","volume":"38","author":"Abrahams","year":"1999","journal-title":"Angew. 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