{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T22:32:18Z","timestamp":1788388338576,"version":"build-2803163510"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2018,8,13]],"date-time":"2018-08-13T00:00:00Z","timestamp":1534118400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,8,13]],"date-time":"2018-08-13T00:00:00Z","timestamp":1534118400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["17-73-10219"],"award-info":[{"award-number":["17-73-10219"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2018,7,10]]},"published-print":{"date-parts":[[2018,9,1]]},"abstract":"<jats:p>The thermal stability of the layered modification of the Cu<jats:sub>0.5<\/jats:sub>ZrTe<jats:sub>2<\/jats:sub> polycrystalline intercalation compound, synthesized at room temperature, has been studied in the temperature range 25\u2013900\u2005\u00b0C. A change in the occupation of the octahedral and tetrahedral coordinated sites in the interlayer space of the zirconium ditelluride was observed using <jats:italic>in-situ<\/jats:italic> time-resolved synchrotron X-ray powder diffraction experiments. The formation of the rhombohedral CuZr<jats:sub>2<\/jats:sub>Te<jats:sub>4<\/jats:sub> phase, which is stable in the temperature range 300\u2013700\u2005\u00b0C, has been observed. The copper intercalation at room temperature leads to the formation of a phase in which the Cu atoms occupy only octahedral sites in the interlayer space. At temperatures above the decay temperature of the rhombohedral CuZr<jats:sub>2<\/jats:sub>Te<jats:sub>4<\/jats:sub>, a layered phase with Cu atoms uniformly distributed between octahedral and tetrahedral sites in the interlayer space is stable. The changes in the crystal structure independent of temperature are in agreement with the previously proposed model, according to which the stability of the layered or the rhombohedral phase is determined by the entropy factor associated with the distribution of the intercalated atoms between the octahedral and tetrahedral sites in the interlayer space.<\/jats:p>","DOI":"10.1107\/s2053229618009841","type":"journal-article","created":{"date-parts":[[2018,8,13]],"date-time":"2018-08-13T14:03:56Z","timestamp":1534169036000},"page":"1020-1025","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":25,"title":["Thermal stability of the layered modification of Cu<sub>0.5<\/sub>ZrTe<sub>2<\/sub> in the temperature range 25\u2013900\u2005\u00b0C"],"prefix":"10.1107","volume":"74","author":[{"given":"E. G.","family":"Shkvarina","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. 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