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Due to a high surface charge density, the paratungstate anion acts as a multidentate ligand forming high-dimensional extended structures, which exhibit unique catalytic and magnetic properties. Two new paradodecatungstate B compounds decorated by iron(II) or copper(II), namely Na<jats:sub>5<\/jats:sub>Fe<jats:sub>2.5<\/jats:sub>[W<jats:sub>12<\/jats:sub>O<jats:sub>40<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]\u00b736H<jats:sub>2<\/jats:sub>O (<jats:bold>Na<jats:sub>5<\/jats:sub>Fe<jats:sub>2.5<\/jats:sub>paraB<\/jats:bold>) and Na<jats:sub>4<\/jats:sub>Cu<jats:sub>3<\/jats:sub>[W<jats:sub>12<\/jats:sub>O<jats:sub>40<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]\u00b728H<jats:sub>2<\/jats:sub>O (<jats:bold>Na<jats:sub>4<\/jats:sub>Cu<jats:sub>3<\/jats:sub>paraB<\/jats:bold>), have been synthesized by a convenient aqueous solution method, and structurally characterized by single-crystal and powder X-ray diffraction, IR spectroscopy, elemental analysis and thermogravimetric analysis. Both compounds crystallize in the triclinic <jats:italic>P<\/jats:italic>\\overline{1} space group. In both compounds, the [W<jats:sub>12<\/jats:sub>O<jats:sub>40<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]<jats:sup>10\u2212<\/jats:sup> polyanion acts as a multidentate ligand that links transition-metal and sodium cations, forming a three-dimensional framework.<\/jats:p>","DOI":"10.1107\/s2053229618010021","type":"journal-article","created":{"date-parts":[[2018,10,16]],"date-time":"2018-10-16T14:56:28Z","timestamp":1539701788000},"page":"1252-1259","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":7,"title":["Iron(II) and copper(II) paratungstates B: a single-crystal X-ray diffraction study"],"prefix":"10.1107","volume":"74","author":[{"given":"Nadiia I.","family":"Gumerova","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anatolie","family":"Dobrov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Roller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5919-0553","authenticated-orcid":true,"given":"Annette","family":"Rompel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,10,16]]},"reference":[{"key":"jr3015_bb1","doi-asserted-by":"crossref","unstructured":"Bijelic, A., Aureliano, M. & Rompel, A. 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