{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T19:16:28Z","timestamp":1774552588904,"version":"3.50.1"},"reference-count":42,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2018,7,27]],"date-time":"2018-07-27T00:00:00Z","timestamp":1532649600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,7,27]],"date-time":"2018-07-27T00:00:00Z","timestamp":1532649600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100004901","name":"FAPEMIG","doi-asserted-by":"crossref","award":["CEX-APQ 01919-17"],"award-info":[{"award-number":["CEX-APQ 01919-17"]}],"id":[{"id":"10.13039\/501100004901","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","award":["307599\/2017-5"],"award-info":[{"award-number":["307599\/2017-5"]}],"id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2018,7,16]]},"published-print":{"date-parts":[[2018,8,1]]},"abstract":"<jats:p>Aromatic polycarboxylate linkers provide structural rigidity and strong interactions among the metal centre and the carboxylate O atoms. A new three-dimensional coordination polymer namely, <jats:italic>catena<\/jats:italic>-poly[potassium [tetraaqua(\u03bc-5-sulfobenzene-1,3-dicarboxylato)zinc(II)]], {K[Zn(C<jats:sub>8<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>7<\/jats:sub>S)(H<jats:sub>2<\/jats:sub>O)<jats:sub>4<\/jats:sub>]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or {K[Zn(SIP)(H<jats:sub>2<\/jats:sub>O)<jats:sub>4<\/jats:sub>]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, where SIP is 5-sulfobenzene-1,3-dicarboxylate or 5-sulfoisophthalate, was obtained and characterized by elemental analysis and IR vibrational spectroscopy, and the single-crystal structure was determined by X-ray diffraction analysis. The compound crystallizes in the monoclinic space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>n<\/jats:italic> with <jats:italic>Z<\/jats:italic> = 4. Topological analysis revealed that K\u2014O interactions form a two-dimensional network, which is uninodal 4-connected and can be described with a point symbol (4<jats:sup>4<\/jats:sup>.6<jats:sup>2<\/jats:sup>), and this plane network is classified as <jats:bold>sql\/Shubnikov<\/jats:bold>. The layers are connected by Zn<jats:sup>2+<\/jats:sup> ions coordinated to the SIP linker, forming a three-dimensional network. This net is a trinodal (3,5,6)-connected system with point symbol (3.4<jats:sup>4<\/jats:sup>.5<jats:sup>2<\/jats:sup>.6<jats:sup>2<\/jats:sup>.7<jats:sup>3<\/jats:sup>.8<jats:sup>3<\/jats:sup>).(3.4<jats:sup>4<\/jats:sup>.5<jats:sup>2<\/jats:sup>.6<jats:sup>2<\/jats:sup>.7).(3.7<jats:sup>2<\/jats:sup>).<\/jats:p>","DOI":"10.1107\/s2053229618010264","type":"journal-article","created":{"date-parts":[[2018,7,27]],"date-time":"2018-07-27T10:41:13Z","timestamp":1532688073000},"page":"981-985","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis, crystal structure and topological analysis of a three-dimensional polymeric network based on zinc(II), potassium and 5-sulfobenzene-1,3-dicarboxylate (SIP)"],"prefix":"10.1107","volume":"74","author":[{"given":"Fl\u00e1via H.","family":"Silva","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chris H. J.","family":"Franco","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Charlane C.","family":"Corr\u00eaa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9042-9094","authenticated-orcid":true,"given":"Renata","family":"Diniz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,7,27]]},"reference":[{"key":"ov3111_bb1","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.jssc.2014.08.009","volume":"220","author":"Ar\u0131c\u0131","year":"2014","journal-title":"J. Solid State Chem."},{"key":"ov3111_bb2","doi-asserted-by":"crossref","first-page":"1715","DOI":"10.1351\/PAC-REC-12-11-20","volume":"85","author":"Batten","year":"2013","journal-title":"Pure Appl. Chem."},{"key":"ov3111_bb3","unstructured":"Batten, S. R., Neville, S. M. & Turner, D. R. (2009). In Coordination Polymers: Design, Analysis and Application. Cambridge, UK: RSC Publishing."},{"key":"ov3111_bb4","unstructured":"Blatov, V. A. & Shevchenko, A. P. (2016). TOPOSPRO. Version 5.3.0.4. http:\/\/topospro.com."},{"key":"ov3111_bb5","doi-asserted-by":"crossref","first-page":"3576","DOI":"10.1021\/cg500498k","volume":"14","author":"Blatov","year":"2014","journal-title":"Cryst. Growth Des."},{"key":"ov3111_bb6","doi-asserted-by":"crossref","first-page":"1804","DOI":"10.1002\/1521-3765(20020415)8:8<1804::AID-CHEM1804>3.0.CO;2-C","volume":"8","author":"Braga","year":"2002","journal-title":"Chem. Eur. J."},{"key":"ov3111_bb7","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1016\/j.inoche.2015.07.018","volume":"60","author":"Chen","year":"2015","journal-title":"Inorg. Chem. Commun."},{"key":"ov3111_bb8","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1016\/j.inoche.2017.10.003","volume":"86","author":"Cheng","year":"2017","journal-title":"Inorg. Chem. Commun."},{"key":"ov3111_bb9","doi-asserted-by":"crossref","first-page":"24594","DOI":"10.1039\/c4ra02291b","volume":"4","author":"Ding","year":"2014","journal-title":"RSC Adv."},{"key":"ov3111_bb10","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"ov3111_bb11","doi-asserted-by":"crossref","first-page":"41461","DOI":"10.1039\/C4RA07629J","volume":"4","author":"Franco","year":"2014","journal-title":"RSC Adv."},{"key":"ov3111_bb12","doi-asserted-by":"crossref","first-page":"978","DOI":"10.1007\/s10904-018-0784-0","volume":"28","author":"Franco","year":"2018","journal-title":"J. Inorg. Organomet. Polym."},{"key":"ov3111_bb13","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1016\/j.jssc.2015.07.008","volume":"230","author":"Guan","year":"2015","journal-title":"J. Solid State Chem."},{"key":"ov3111_bb14","doi-asserted-by":"crossref","first-page":"947","DOI":"10.1080\/00958972.2016.1141200","volume":"69","author":"Guan","year":"2016","journal-title":"J. Coord. Chem."},{"key":"ov3111_bb15","doi-asserted-by":"crossref","first-page":"5657","DOI":"10.1039\/C4CS00032C","volume":"43","author":"He","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb16","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1134\/S0022476616060305","volume":"57","author":"Hou","year":"2016","journal-title":"J. Struct. Chem."},{"key":"ov3111_bb17","doi-asserted-by":"crossref","first-page":"2334","DOI":"10.1002\/anie.200300610","volume":"43","author":"Kitagawa","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"ov3111_bb18","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1039\/b313997m","volume":"34","author":"Kitagawa","year":"2005","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb19","doi-asserted-by":"crossref","first-page":"1105","DOI":"10.1021\/cr200324t","volume":"112","author":"Kreno","year":"2012","journal-title":"Chem. Rev."},{"key":"ov3111_bb20","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.molstruc.2004.04.018","volume":"698","author":"Kubicki","year":"2004","journal-title":"J. Mol. Struct."},{"key":"ov3111_bb21","doi-asserted-by":"crossref","first-page":"1477","DOI":"10.1039\/b802426j","volume":"38","author":"Li","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb22","doi-asserted-by":"crossref","first-page":"14241","DOI":"10.1039\/c4ra00531g","volume":"4","author":"Li","year":"2014","journal-title":"RSC Adv."},{"key":"ov3111_bb23","doi-asserted-by":"crossref","first-page":"1157","DOI":"10.1002\/ejic.200701147","author":"Liu","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ov3111_bb24","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Cryst."},{"key":"ov3111_bb25","doi-asserted-by":"crossref","first-page":"1294","DOI":"10.1039\/b802256a","volume":"38","author":"Murray","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb26","doi-asserted-by":"crossref","first-page":"1782","DOI":"10.1021\/ar800124u","volume":"41","author":"O'Keeffe","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"ov3111_bb27","doi-asserted-by":"crossref","first-page":"6116","DOI":"10.1039\/C4CS00159A","volume":"43","author":"Qiu","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb28","unstructured":"Rigaku OD (2015). CrysAlis PRO. Version 171.38.41. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England."},{"key":"ov3111_bb29","doi-asserted-by":"crossref","first-page":"1081","DOI":"10.1039\/c0cs00147c","volume":"40","author":"Shekhah","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb30","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ov3111_bb31","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ov3111_bb32","doi-asserted-by":"crossref","first-page":"7009","DOI":"10.1039\/C7CE01453H","volume":"19","author":"Singh","year":"2017","journal-title":"CrystEngComm"},{"key":"ov3111_bb33","doi-asserted-by":"crossref","first-page":"933","DOI":"10.1021\/cr200304e","volume":"112","author":"Stock","year":"2012","journal-title":"Chem. Rev."},{"key":"ov3111_bb34","doi-asserted-by":"crossref","first-page":"782","DOI":"10.1021\/cr200274s","volume":"112","author":"Suh","year":"2012","journal-title":"Chem. Rev."},{"key":"ov3111_bb35","doi-asserted-by":"crossref","first-page":"1257","DOI":"10.1039\/b817735j","volume":"38","author":"Tranchemontagne","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ov3111_bb36","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1016\/j.poly.2013.09.002","volume":"67","author":"Voda","year":"2014","journal-title":"Polyhedron"},{"key":"ov3111_bb37","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"ov3111_bb38","doi-asserted-by":"crossref","first-page":"705","DOI":"10.1038\/nature01650","volume":"423","author":"Yaghi","year":"2003","journal-title":"Nature"},{"key":"ov3111_bb39","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/j.ccr.2014.12.009","volume":"293-294","author":"Zhang","year":"2015","journal-title":"Coord. Chem. Rev."},{"key":"ov3111_bb40","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1071\/CH17498","volume":"71","author":"Zhang","year":"2018","journal-title":"Aust. J. Chem."},{"key":"ov3111_bb41","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1007\/s10870-012-0381-y","volume":"43","author":"Zhou","year":"2013","journal-title":"J. Chem. Crystallogr."},{"key":"ov3111_bb42","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1016\/j.inoche.2016.10.009","volume":"73","author":"Zhu","year":"2016","journal-title":"Inorg. Chem. Commun."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2018\/08\/00\/ov3111\/ov3111.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2018\/08\/00\/ov3111\/ov3111.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:11:58Z","timestamp":1736766718000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229618010264"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,7,27]]},"references-count":42,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2018,8]]}},"alternative-id":["S2053229618010264"],"URL":"https:\/\/doi.org\/10.1107\/s2053229618010264","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229618010264\/ov3111sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229618010264\/ov3111Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,7,27]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?ov3111","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"26 February 2018","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"16 July 2018","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"27 July 2018","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ov3111"}},{"value":"\u00a9 2018 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}