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A new coordination polymer, namely poly[[\u03bc<jats:sub>2<\/jats:sub>-1,6-bis(pyridin-3-yl)-1,3,5-hexatriene-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032](\u03bc<jats:sub>3<\/jats:sub>-naphthalene-1,4-dicarboxylato-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>O<\/jats:italic>\n                  <jats:sup>1\u2032<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>4\u2032<\/jats:sup>)zinc(II)], [Zn(C<jats:sub>12<\/jats:sub>H<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>16<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, has been prepared by the self-assembly of Zn(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b76H<jats:sub>2<\/jats:sub>O, naphthalene-1,4-dicarboxylic acid (1,4-H<jats:sub>2<\/jats:sub>ndc) and 1,6-bis(pyridin-3-yl)-1,3,5-hexatriene (3,3\u2032-bphte) under hydrothermal conditions. The title compound has been structurally characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and single-crystal X-ray diffraction analysis. Each Zn<jats:sup>II<\/jats:sup> ion is six-coordinated by four O atoms from three 1,4-ndc<jats:sup>2\u2212<\/jats:sup> ligands and by two N atoms from two 3,3\u2032-bphte ligands, forming a distorted octahedral ZnO<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub> coordination geometry. Pairs of Zn<jats:sup>II<\/jats:sup> ions are linked by 1,4-ndc<jats:sup>2\u2212<\/jats:sup> ligands, leading to the formation of a two-dimensional square lattice (<jats:bold>sql<\/jats:bold>) layer extending in the <jats:italic>ab<\/jats:italic> plane. In the crystal, adjacent layers are further connected by 3,3\u2032-bphte bridges, generating a three-dimensional architecture. From a topological viewpoint, if each dinuclear zinc unit is considered as a 6-connected node and the 1,4-ndc<jats:sup>2\u2212<\/jats:sup> and 3,3\u2032-bphte ligands are regarded as linkers, the structure can be simplified as a unique three-dimensional 6-connected framework with the point symbol 4<jats:sup>4<\/jats:sup>6<jats:sup>10<\/jats:sup>8. The thermal stability and solid-state photoluminescence properties have also been investigated.<\/jats:p>","DOI":"10.1107\/s2053229618012068","type":"journal-article","created":{"date-parts":[[2018,8,29]],"date-time":"2018-08-29T15:07:39Z","timestamp":1535555259000},"page":"1053-1057","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Construction and photoluminescence properties of a three-dimensional Zn<sup>II<\/sup> coordination network based on naphthalene-1,4-dicarboxylic acid and 1,6-bis(pyridin-3-yl)-1,3,5-hexatriene"],"prefix":"10.1107","volume":"74","author":[{"given":"Qian-Kun","family":"Zhou","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lin","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yun","family":"Xu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ni-Ya","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,8,29]]},"reference":[{"key":"yp3161_bb1","doi-asserted-by":"crossref","first-page":"2189","DOI":"10.1039\/C6CE00284F","volume":"18","author":"Aulakh","year":"2016","journal-title":"CrystEngComm"},{"key":"yp3161_bb2","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1039\/B910671E","volume":"12","author":"Blatov","year":"2010","journal-title":"CrystEngComm"},{"key":"yp3161_bb3","doi-asserted-by":"crossref","first-page":"3576","DOI":"10.1021\/cg500498k","volume":"14","author":"Blatov","year":"2014","journal-title":"Cryst. 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