{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:21:01Z","timestamp":1740172861145,"version":"3.37.3"},"reference-count":34,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2018,10,18]],"date-time":"2018-10-18T00:00:00Z","timestamp":1539820800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,10,18]],"date-time":"2018-10-18T00:00:00Z","timestamp":1539820800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2018,11,1]]},"abstract":"<jats:p>3,5-Bis[(1<jats:italic>H<\/jats:italic>-tetrazol-5-yl)methyl]-4<jats:italic>H<\/jats:italic>-1,2,4-triazol-4-amine (H<jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>) associates under deprotonation with CuSO<jats:sub>4<\/jats:sub> in aqueous medium to form a new waisted barrel-shaped <jats:italic>M<\/jats:italic>\n                  <jats:sub>6<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>\n                  <jats:sub>4<\/jats:sub> cluster, namely hexaaquatetrakis{\u03bc<jats:sub>4<\/jats:sub>-3,5-bis[(1<jats:italic>H<\/jats:italic>-tetrazol-5-yl)methyl]-4<jats:italic>H<\/jats:italic>-1,2,4-triazol-4-amine}-\u03bc<jats:sub>4<\/jats:sub>-sulfato-hexacopper(II) sulfate hydrate, [Cu<jats:sub>6<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>12<\/jats:sub>)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>]SO<jats:sub>4<\/jats:sub>\u00b7<jats:italic>n<\/jats:italic>H<jats:sub>2<\/jats:sub>O (<jats:italic>n<\/jats:italic> = \u223c23) (<jats:bold>1<\/jats:bold>). Cluster <jats:bold>1<\/jats:bold> resembles concave cucurbit[6]uril and has one disordered sulfate anion trapped inside the cage, which additionally stabilizes the Cu<jats:sub>6<\/jats:sub> unit. The Cu<jats:sup>II<\/jats:sup> ions have either a square-pyramidal or a distorted octahedral geometry. The equatorial positions are filled by N atoms from the <jats:italic>L<\/jats:italic>\n                  <jats:sup>2\u2212<\/jats:sup> ligand, while the axial positions are occupied by coordinated water molecules and O atoms of the sulfate counter-ion. In the solid state, the Cu<jats:sub>6<\/jats:sub> clusters are connected through a large number of hydrogen bonds formed by uncoordinated water molecules and an additional sulfate anion. The compound shows good antimicrobial activity against <jats:italic>E. coli<\/jats:italic> tested with the Kirby Bauer approach. In addition, the cell viability towards HeLa and L-929 cells was studied.<\/jats:p>","DOI":"10.1107\/s2053229618013670","type":"journal-article","created":{"date-parts":[[2018,10,18]],"date-time":"2018-10-18T14:21:21Z","timestamp":1539872481000},"page":"1413-1419","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Solid-state structure and antimicrobial and cytotoxicity studies of a cucurbit[6]uril-like Cu<sub>6<\/sub>\n                  <i>L<\/i>\n                  <sub>4<\/sub> constructed from 3,5-bis[(1<i>H<\/i>-tetrazol-5-yl)methyl]-4<i>H<\/i>-1,2,4-triazol-4-amine"],"prefix":"10.1107","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6219-6051","authenticated-orcid":true,"given":"Serhii","family":"Vasylevskyi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anja","family":"Holzheu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1168-0123","authenticated-orcid":true,"given":"Katharina M.","family":"Fromm","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,10,18]]},"reference":[{"key":"sk3703_bb1","doi-asserted-by":"crossref","first-page":"238","DOI":"10.1002\/chem.19960020217","volume":"2","author":"Ahlrichs","year":"1996","journal-title":"Chem. 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