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These compounds were isolated using a one-pot synthetic strategy with copper, lanthanoid, trilacunary arsenotungstate and 1,10-phenanthroline as precursors. They were characterized using various analytical techniques, such as single-crystal X-ray diffraction (SC-XRD), powder XRD (PXRD), Fourier transform IR (FT\u2013IR) spectroscopy, UV\u2013Vis spectroscopy and thermogravimetric analysis (TGA). In all these compounds, a dinuclear Ln<jats:sub>2<\/jats:sub>(ac)<jats:sub>2<\/jats:sub> moiety is sandwiched between two monolacunary [AsW<jats:sub>11<\/jats:sub>O<jats:sub>39<\/jats:sub>]<jats:sup>7\u2212<\/jats:sup> polyoxometalates (POMs), where the Ln<jats:sub>2<\/jats:sub>(ac)<jats:sub>2<\/jats:sub> moiety is comprised of two acetate ligands in a \u03bc-\u03ba<jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>\u2032:\u03ba<jats:italic>O<\/jats:italic> fashion. Moreover, the anion is decorated by a copper\u2013phenanthroline\u2013acetate complex through a terminal O atom of the polyanion.<\/jats:p>","DOI":"10.1107\/s2053229618014171","type":"journal-article","created":{"date-parts":[[2018,11,29]],"date-time":"2018-11-29T17:06:03Z","timestamp":1543511163000},"page":"1561-1568","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Synthesis and characterization of self-assembled inorganic\u2013organic hybrid arsenotungstates"],"prefix":"10.1107","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8514-8781","authenticated-orcid":true,"given":"Swati","family":"Parbhakar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Reetam","family":"Kaushik","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0639-7638","authenticated-orcid":true,"given":"Firasat","family":"Hussain","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,11,30]]},"reference":[{"unstructured":"Agilent (2013). 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